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有机化学
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有机化学 ›› 2003, Vol. 23 ›› Issue (9): 1008-1012. 上一篇    下一篇

研究论文

聚（琥珀酸丁二醇酯-共-富马酸丁二醇酯）的合成及其双羟基化反应研究

张世平;杨晶;刘小云;常建华;曹阿民   

  1. 西北大学化学系;中国科学院上海有机化学研究所高分子研究室
  • 发布日期:2003-09-25

Studies on the Synthesis of Poly(butylene Succinate-co-butylene Fumarate) and Dihydroxylation of Their C=C Double Bonds

Zhang Shiping;Yang Jing;Liu Xiaoyun;Chang Jianhua;Cao Amin   

  1. Department of Chemistry, Northwest University;Polymer Laboratory, Shanghai Institute of Organic Chemistry
  • Published:2003-09-25

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1011

被引次数

11

以琥珀酸、富马酸、丁二醇为原料，用共缩聚的方法合成了一系列高分子量聚 （琥珀酸丁二醇酯-共-富马酸丁二醇酯）。然后在催化剂四氧化锇和N-甲基吗啉- N-氧化物以及水存在下，使高分子主链中富马酸丁二醇酯共聚单元的碳碳不饱和双 键发生羟基化反应得到含有亲水性侧羟基的功能性聚酯。对上述合成的生物降解性 高分子运用核磁共振（NMR）、红外（FT-IR）、热分析等方法进行了结构与物理性 能表征。

关键词: 琥珀酸;富马酸;丁二醇;氧化锇;吗啉 P;羟基化;核磁共振谱法;傅里叶变换, 红外分光光度法;结构表征;聚合物

From starting materials of succinic acid, fumaric acid and 1,4- butanediol, a series of poly (butylene succinate-co-butylene fumarate)s [P(BS-co-BF)] bearing various BF comonomer molar contents were synthesized. Subsequently, the carbon double bonds involved in the copolyester main chain were subjected to dihydroxylation with catalyst of osmium tetroxide (OSO4) , 7V-methyhnorpholine ./V-oxide (NMO) and water to prepare novel biodegradable copolyesters bearing hydrophilic hydroxyl pendant groups. Moreover, these synthesized copolyesters were further characterized by NMR, FT-IR, DSC.

Key words: succinic acid;fumaric acid;BUTANEDIOL;OSMIUM OXIDE;MORPHOLINE P, HYDROXYLATION;NMR;FT;IR;STRUCTURE CHARACTERISTICS;POLYMER

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