Twelve novel chenodeoxycholic acid-based molecular tweezer metal receptors containing 1,2,3-triazole moieties have been designed and synthesized using click chemistry method. The target compounds were characterized by 1H NMR, IR, MS spectra and elemental analysis. Their binding properties were examined by UV-Vis spectra titration. The results indicate that these molecular tweezers showed high selectivity and affinity for Hg2+ ion.
赵志刚, 王晓红, 石治川, 程玉宇. 通过点击化学方法合成鹅去氧胆酸类分子钳及其识别性能研究[J]. 有机化学, 2014, 34(6): 1110-1117.
Zhao Zhigang, Wang Xiaohong, Shi Zhichuan, Cheng Yuyu. Synthesis of Molecular Tweezers Derived from Chenodeoxycholic Acid through Click Reaction and Their Recogniton Properties. Chin. J. Org. Chem., 2014, 34(6): 1110-1117.
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