有机化学 ›› 2017, Vol. 37 ›› Issue (10): 2745-2751.DOI: 10.6023/cjoc201704001 上一篇    下一篇

研究论文

三价磷化合物与亲电氟化试剂Selectfluor的氟化反应

黄昱霖a, 陈迁a,b   

  1. a 广东工业大学轻工化工学院 广州 510006;
    b 华南理工大学 广东省功能分子工程重点实验室 广州 510640
  • 收稿日期:2017-04-01 修回日期:2017-05-10 出版日期:2017-10-25 发布日期:2017-06-02
  • 通讯作者: 陈迁 E-mail:qianchen@gdut.edu.cn
  • 基金资助:

    广东省科技计划(No.2015A020211026)、广东工业大学青年百人计划(No.220413506)和广东省功能分子工程重点实验室(No.2016kf07)资助项目.

Fluorination Reaction of P(Ⅲ) Compounds with the Electrophilic Fluorinating Reagent Selectfluor

Huang Yulina, Chen Qiana,b   

  1. a School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006;
    b Key Laboratory of Functional Molecular Engineering of Guangdong Province, South China University of Technology, Guangzhou 510640
  • Received:2017-04-01 Revised:2017-05-10 Online:2017-10-25 Published:2017-06-02
  • Contact: 10.6023/cjoc201704001 E-mail:qianchen@gdut.edu.cn
  • Supported by:

    Project supported by the Science and Technology Planning Project of Guangdong Province (No.2015A020211026),the 100 Young Talents Program of Guangdong University of Technology (No.220413506) and the Open Fund of the Key Laboratory of Functional Molecular Engineering of Guangdong Province (No.2016kf07).

报道了三价磷化合物与亲电氟化试剂Selectfluor的氟化反应,反应以乙腈/水为溶剂、室温条件下反应15~60 min,以34%~81%的收率得到了磷酰氟类化合物.

关键词: 三价磷化合物, 亲电氟化试剂, 氟化反应, 磷酰氟

A fluorination reaction of P(Ⅲ) compounds with the electrophilic fluorinating reagent Selectfluor is described. The reaction proceeded in acetonitrile/water at room temperature for 15~60 min to afford phosphoric fluorides in 34%~81% yields.

Key words: P(Ⅲ) compound, electrophilic fluorinating reagent, fluorination reaction, phosphoric fluoride