Chin. J. Org. Chem. ›› 2013, Vol. 33 ›› Issue (01): 36-45.DOI: 10.6023/cjoc201208028 Previous Articles     Next Articles



王丽丽, 田荣强, 段征, Francois Mathey   

  1. 郑州大学化学与分子工程学院 郑州 450001
  • 收稿日期:2012-08-27 修回日期:2012-09-19 发布日期:2012-09-24
  • 通讯作者: 段征
  • 基金资助:

    国家自然科学基金(No. 21072179)资助项目.

Recent Advances of [1,5]-Sigmatropic Shift of Phospholes

Wang Lili, Tian Rongqiang, Duan Zheng, Mathey Francois   

  1. College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001
  • Received:2012-08-27 Revised:2012-09-19 Published:2012-09-24
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No. 21072179).

Phosphole plays an important role in the modern organophosphorus chemistry. Due to its structure specialities, the exocyclic P—R σ bond shows significant interaction with the π* orbital of the dienic system and this overlap favors the [1,5]-sigmatropic shift of the substitutent (R) of P from phosphorus to carbon. This provides an efficient method to prepare various functionalized phospholes. This review is concerning the recent application of [1,5]-sigmatropic shift of phospholes in the organophosphorus and material chemistry.

Key words: phosphole, [1,5]-sigmatropic shift, organophosphorus