Chin. J. Org. Chem. ›› 2014, Vol. 34 ›› Issue (1): 210-214.DOI: 10.6023/cjoc201307045 Previous Articles     Next Articles



王彬彬, 钱鹰   

  1. 东南大学化学化工学院 南京 211189
  • 收稿日期:2013-07-29 修回日期:2013-09-12 发布日期:2013-09-25
  • 通讯作者: 钱鹰
  • 基金资助:

    国家自然科学基金(No. 61178057)资助项目.

Synthesis, Multiphoton Absorption and Fluorescence Properties of a Push-Pull A-D-A Anthracene

Wang Binbin, Qian Ying   

  1. School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189
  • Received:2013-07-29 Revised:2013-09-12 Published:2013-09-25
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No. 61178057).

A acceptor-donor-acceptor push-pull anthracene, 9,10-bis{4-{2-N,N-bis-{4-{4-[5-(4-tert-butylphenyl)-1,3,4-oxadiazol-2-yl]-styryl}phenyl}amino}styryl}anthracene (An-BPOAS) was synthesized by Heck reaction of 9,10-bis{4-[N,N-(4-iodophenyl)amino]styryl}anthracene (An-BIPAS) with aryl ethene. The multiphoton absorption and multiphoton induced fluorescence properties of An-BPOAS were measured using a femtosecond Ti:sapphire laser. When pumped with 1300 nm femtosecond laser irradiation, chromophores An-BPOAS and An-BIPAS show fluorescence at 539 and 553 nm, three-photon absorption cross-sections determined by nonlinear transmission method are 1.5×10-5 cm3/GW2 for An-BPOAS and 0.3×10-5 cm3/GW2 for An-BIPAS. The linear absorption and fluorescence properties of An-BPOAS were measured. The fluorescent behaviour of An-BPOAS in different pH was studied.

Key words: 9,10-diaryl anthracene derivatives, Heck reaction, fluorescence properties, multiphoton absorption, multiphoton induced fluorescence