Chin. J. Org. Chem. ›› 2014, Vol. 34 ›› Issue (4): 681-692.DOI: 10.6023/cjoc201310019 Previous Articles     Next Articles



刘课艳, 偶辉, 石先莹, 董雪芬, 马文娟, 魏俊发   

  1. 陕西师范大学化学化工学院 陕西省大分子科学重点实验室 西安 710062
  • 收稿日期:2013-10-16 修回日期:2013-11-25 发布日期:2013-12-18
  • 通讯作者: 石先莹,魏俊发;
  • 基金资助:

    国家自然科学基金(Nos. 21072123,21272145)、中央高校基本科研业务费专项资金(Nos. GK201102005,GK261001095)资助项目

Recent Progress in the Selective Oxidation of Sulfides withHydrogen Peroxide

Liu Keyan, Ou Hui, Shi Xianying, Dong Xuefen, Ma Wenjuan, Wei Junfa   

  1. Key Laboratory for Macromolecular Science of Shaanxi Province, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an 710062
  • Received:2013-10-16 Revised:2013-11-25 Published:2013-12-18
  • Supported by:

    Project supported by the National Natural Science Foundation of China (Nos. 21072123, 21272145), the Fundamental Research Funds for the Central Universities (Nos. GK201102005, GK261001095).

Sulfoxides and sulfones have broad applications in pharmaceutical agents and pesticide due to their biologically activities and they are important synthetic intermediates in C—C bond formation and various molecular rearrangements. The selective oxidation of sulfides is a straightforward and frequently used method to obtain sulfoxides and sulfones. Among various oxidizing agents, hydrogen peroxide as benign oxidant has attracted organic chemists' attention for a long time. This review summarizes the recent and important catalytic systems of metal and nonmetal in this area. The catalytic effect of different catalytic systems is briefly discussed herein.

Key words: catalytic oxidation, sulfides, sulfones, sulfoxides, hydrogen peroxide