Chin. J. Org. Chem. ›› 2014, Vol. 34 ›› Issue (11): 2224-2235.DOI: 10.6023/cjoc201405005 Previous Articles     Next Articles

苯并咪唑类过渡金属配合物: 新型乙烯齐聚与聚合催化剂

肖立伟, 李玲玲, 高红杰, 任萍, 寇伟, 时亚茹   

  1. 廊坊师范学院化学与材料科学学院 廊坊 065000
  • 收稿日期:2014-05-05 修回日期:2014-06-06 发布日期:2014-07-02
  • 通讯作者: 肖立伟,
  • 基金资助:


Benzimidazoles-Containing Transition Metal Complexes: A Novel Catalyst for Ethylene Oligomerization and Polymerization

Xiao Liwei, Li Lingling, Gao Hongjie, Ren Ping, Kou Wei, Shi Yaru   

  1. Faculty of Chemistry and Material Science, Langfang Teachers University, Langfang 065000
  • Received:2014-05-05 Revised:2014-06-06 Published:2014-07-02
  • Supported by:

    Project supported by the Natural Science Foundation of Hebei Province (No.B2013408014) and the Key Foundation of Langfang Teachers University (No.LSZZ201302).

Benzimidazole heterocycles have good selectivity for coordination and can form a variety of metal complexes, which exhibit excellent biological, fluorescence and catalytic properties. In this paper, the progress for synthesis of benzimidazoles-containing transition metal complexes and their catalytic activity for ethylene oligomerization and polymerization are summarized, and the influence of the structural factor of complexes such as electronic effect and steric effect of substituent group on the catalytic performance is discussed.

Key words: benzimidazole, coordination catalysis, ethylene oligomerization and polymerization, structure-activity relationship