Chin. J. Org. Chem. ›› 2015, Vol. 35 ›› Issue (3): 578-587.DOI: 10.6023/cjoc201410046 Previous Articles     Next Articles



范文佳, 陈丽君, 杨海波   

  1. 华东师范大学化学系 上海市绿色化学与化工过程绿色化重点实验室 上海 200062
  • 收稿日期:2014-10-31 修回日期:2014-12-02 发布日期:2015-01-07
  • 通讯作者: 陈丽君, 杨海波;
  • 基金资助:

    上海市科委基础重点(No. 13JC1402200)与优秀博士学位论文培育行动计划(No. PY2014011)资助项目.

Supramolecular Organometallic Gels Based on Neutral Platinum-Acetylide Moiety

Fan Wenjia, Chen Lijun, Yang Haibo   

  1. Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, Shanghai 200062
  • Received:2014-10-31 Revised:2014-12-02 Published:2015-01-07
  • Supported by:

    Project supported by the Key Basic Research Project of Shanghai Science and Technology Commission (No. 13JC1402200) and the Outstanding Doctoral Dissertation Cultivation Plan of Action (No. PY2014011).

Supramolecular gels, as a family of classical soft materials, have received considerable attention because of their wide potential applications in catalysis, chemical sensing, drug delivery carrier, and many other areas. Recently, it was found that the introduction of metal moieties, especially the transition metal moieties into the gelator allows for the additional scope for tuning gel properties such as catalytic activity, magnetism, and photo- and electrochemistry. Neutral platinum-acetylide complex have been investigated in many respects from supramolecular chemistry to materials science during the past two decades because of their attractive properties such as well-defined linear geometry, synthetic accessibility and intriguing photoproperties. In this review article, we summarize the recent results in the investigation of supramolecular organometallic gels based on neutral platinum-acetylide moieties. These systems are classified based on the skeleton of the gelator building blocks and divided into two main parts, conjugated phenylene cored platinum-acetylide derivatives as well as other platinum-acetylide derivatives containing various functional groups.

Key words: supramolecular chemistry, self-assembly, organometallic gels, platinum-acetylide moiety, π-conjugated system