Transition-Metal-Catalyzed C—H Alkynylation

doi:10.6023/cjoc201412048

Chin. J. Org. Chem. ›› 2015, Vol. 35 ›› Issue (3): 570-577.DOI: 10.6023/cjoc201412048 Previous Articles Next Articles

REVIEW

过渡金属催化的C—H炔基化反应

王明明^a, 王子潇^b, 商明^a, 戴辉雄^a

a 中国科学院上海有机化学研究所金属有机化学国家重点实验室上海 200032;
b 上海大学化学系上海大学创新药物研究中心上海 200444

收稿日期:2014-12-29 修回日期:2015-01-26 发布日期:2015-01-28
通讯作者: 戴辉雄 E-mail:hxdai@sioc.ac.cn
基金资助:
国家自然科学基金(No. 21472211)资助项目.

Transition-Metal-Catalyzed C—H Alkynylation

Wang Mingming^a, Wang Zixiao^b, Shang Ming^a, Dai Huixiong^a

a State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032;
b Department of Chemistry, Innovative Drug Research Center, Shanghai University, Shanghai 200444

Received:2014-12-29 Revised:2015-01-26 Published:2015-01-28
Supported by:
Project supported by the National Natural Science Foundation of China (No. 21472211).

Alkynyl compounds are paramount skeletons in pharmaceuticals and natural products, and great importance has been attached to its synthesis by organic chemists. Recently, transition-metal-catalyzed C—H alkynylation has attracted tremendous interest as a valuable tool for construction of alkynyl compounds. This review gives a summary of progress having been made in the field of the C(sp²)—H and C(sp³)—H alkynylation over the last ten years.

Key words: alkynylation, C—H activation, alkyne, cross dehydrogen coupling

Cite this article

Wang Mingming, Wang Zixiao, Shang Ming, Dai Huixiong. Transition-Metal-Catalyzed C—H Alkynylation[J]. Chin. J. Org. Chem., 2015, 35(3): 570-577.

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过渡金属催化的C—H炔基化反应

Transition-Metal-Catalyzed C—H Alkynylation

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