Chin. J. Org. Chem. ›› 2015, Vol. 35 ›› Issue (11): 2259-2274.DOI: 10.6023/cjoc201504042 Previous Articles     Next Articles



张诗浓a,b, 杨胜虎a, 黄乐浩a, 赵保丽a, 程凯a, 齐陈泽a   

  1. a 绍兴文理学院 浙江省精细化学品传统工艺替代技术研究重点实验室 绍兴 312000;
    b 绍兴市质量技术监督检测院 绍兴 312000
  • 收稿日期:2015-04-27 修回日期:2015-06-19 发布日期:2015-07-08
  • 通讯作者: 程凯
  • 基金资助:

    国家自然科学基金(No. 21402123)、浙江省自然科学基金(Nos. LQ14B020001, LQ14B020001)、浙江省大学生科技创新活动计划(No. 2014R426012)、浙江省教育厅(No. Y201328443)和绍兴市科技计划(No. 2013B70018)资助项目.

Research Progress on Cross-Coupling with Aryl Sulfonyl andSulfinate Compounds

Zhang Shinonga,b, Yang Shenghua, Huang Lehaoa, Zhao Baolia, Cheng Kaia, Qi Chenzea   

  1. a Zhejiang Key Laboratory of Alternative Technologies for Fine Chemicals Process, Shaoxing University, Shaoxing 312000;
    b Shaoxing Testing institute of Quality Technical Supervision, Shaoxing 312000
  • Received:2015-04-27 Revised:2015-06-19 Published:2015-07-08
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No. 21402123), the Zhejiang Provincial Natural Science Foundation (Nos. LQ14B020001, LQ13B020001), the Undergraduate Science Technology Innovation of Zhejiang Province (No. 2014R426012), the Education Department of Zhejiang Province (No. Y201328443) and the Foundation of Science and Technology Bureau of Shaoxing (No. 2013B70018).

Cross-coupling reactions of aryl sulfonyl and sulfinate compounds have been well developed as an efficient synthetic method in recent years. Aryl sulfonyl chlorides, arylsulfinates and arylsulfonyl hydrazides have been used as desulfitative arylation, arylsulfonylation and reductive aryl sulfidation reagents in the synthesis of biaryls, aryl sulfones and aryl sulfides. The research progress on cross-coupling with aryl sulfonyl and sulfinate compounds combined with our work is reviewed, focusing on applications and progress in new synthetic method to construct carbon-carbon, carbon-sulfonyl and carbon-sulfur bond.

Key words: aryl sulfonyl compounds, arylsulfinate compounds, cross-coupling, arylation, arylsulfonylation, aryl sulfidation