Chin. J. Org. Chem. ›› 2016, Vol. 36 ›› Issue (8): 1765-1778.DOI: 10.6023/cjoc201604010 Previous Articles     Next Articles


不同价态Mn(II, III, V)催化的烯烃环氧化反应研究进展

邹晓川a,b, 石开云a, 李俊a, 王跃a, 王存a, 邓朝芳a, 任彦荣a, 谭君a, 傅相锴b   

  1. a 重庆第二师范学院生物与化学工程系 南岸 400067;
    b 西南大学化学化工学院应用化学研究所 重庆市应用化学重点实验室 三峡库区生态环境教育部重点实验室 北碚 400715
  • 收稿日期:2016-04-05 修回日期:2016-05-03 发布日期:2016-06-01
  • 通讯作者: 石开云, 傅相锴,
  • 基金资助:

    重庆市基础与前沿研究(Nos. cstc2015jcyjA0317,cstc2013jcyjA50033)、重庆市教育委员会科学技术研究(Nos. KJ1501411,KJ131513,KJ131512)、重庆市高校创新团队研究(No. KJTD201325)、重庆第二师范学院绿色合成与分析检测重点实验室(No. 16xjpt08)、重庆第二师范学院创新团队(No. KYC-cxtd03-20141z02)资助项目.

Research Progress on Epoxidation of Olefins Catalyzed by Mn(II, III, V) in Different Valence States

Zou Xiaochuana,b, Shi Kaiyuna, Li Juna, Wang Yuea, Wang Cuna, Deng Chaofanga, Ren Yanronga, Tan Juna, Fu Xiangkaib   

  1. a Department of Biological and Chemical Engineering, Chongqing University of Education, Nan'an 400067;
    b Key Laboratory of Applied Chemistry of Chongqing Municipality, Key Laboratory of Eco-environments in Three Gorges Reservoir Region Ministry of Education, Research Institute of Applied Chemistry, College of Chemistry and Chemical Engineering, Southwest University, Beibei 400715
  • Received:2016-04-05 Revised:2016-05-03 Published:2016-06-01
  • Supported by:

    Projects supported by the Basic and Frontier Research Project of Chongqing (Nos. cstc2015jcyjA0317, cstc2013jcyjA50033), the Scientific and Technological Research Program of Chongqing Municipal Education Commission (Nos. KJ1501411, KJ131513, KJ131512), the Innovation Team Building at Institutions of Higher Education in Chongqing (No. KJTD201325), the Key Laboratory of Green Synthesis and Analysis of Chongqing University of Education (No. 16xjpt08) and the Innovative Research Team in Chongqing University of Education (No. KYC-cxtd03-20141002).

The epoxidation catalyzed by transition metals (Cr, Ni, Co, Ru, Mn) has been received widespread attention over the past decades, and the corresponding epoxides are widely used in the synthesis of pharmaceuticals, fine chemicals and pesticides. Compared to other transition metals, metal Mn catalyst has been widely used in organic synthesis due to its inexpensive, environment-friendly, chemical stability and high catalytic activity. This paper reviews the recent progress on epoxidation of olefins catalyzed by the catalysts which were formed by the reaction of different valence metal Mn(II, III, and V) and different NXOY ligands in different oxidants/co-catalyst systems. At the same time, the Mn catalysts with different valence states are involved in the process of the epoxidation of olefins and the mechanism of how to transfer the oxygen of reactive intermediates to the olefins was discussed.

Key words: metal manganese(II, III, V) catalysts, ligands, epoxidation, organic polymer/inorganic phosphate melt (Zr, Zn, Al, Ca), catalytic mechanism