Chin. J. Org. Chem. ›› 2017, Vol. 37 ›› Issue (1): 31-39.DOI: 10.6023/cjoc201607003 Previous Articles     Next Articles



黄房生a,b, 陈训a, 谢应a, 曾伟a   

  1. a 华南理工大学化学与化工学院 广州 510640;
    b 英德市良仕工业材料有限公司 清远 513059
  • 收稿日期:2016-07-02 修回日期:2016-08-19 发布日期:2016-09-06
  • 通讯作者: 曾伟
  • 基金资助:

    国家自然科学基金(No. 21372085)、广州市科技计划项目(No.156300075)和清远市科技计划(No.2014D006)资助项目.

Progress in the Transition Metal-Catalyzed C(sp2)-H Bond Functionalization of Azoarenes

Huang Fangshenga,b, Chen Xuna, Xie Yinga, Zeng Weia   

  1. a School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640;
    b Yingde Liangshi Industrial Material Co. Ltd, Qingyuan 513059
  • Received:2016-07-02 Revised:2016-08-19 Published:2016-09-06
  • Supported by:

    Project supported by the National Natural Science Foundation of China(No. 21372085), the Science and Technology Program of Guangzhou City(No. 156300075) and the Science and Technology Program of Qingyuan(No.2014D006).

Developing simple and concise methods to construct azoarene derivatives has aroused wide concerns due to that these compounds are widely used in the fields of organic dyes,medicines,protein probe and functional materials.As a highly atom- and step-economical approach to making these compounds,transition metal-catalyzed azo group-directed C(sp2)-H bond functionalization provides an efficient synthetic method to regioselectively assemble azoarenes.The reaction types about diverse C(sp2)-H bond functionalzation of azoarenes were summarized in this paper.

Key words: azoarenes, transition metal catalysis, C(sp2)-H bond functionalization, directing groups