Chin. J. Org. Chem. ›› 2017, Vol. 37 ›› Issue (1): 1-19.DOI: 10.6023/cjoc201607040 Previous Articles     Next Articles

Special Issue: 高被引论文合辑(2017-2018)

REVIEW

可见光促进的叔胺C-H官能团化反应

刘薇a, 郑昕宇a, 曾建国a,b, 程辟a,b   

  1. a 湖南农业大学园艺园林学院 兽用中药资源与中兽药创制国家地方联合工程研究中心 长沙 410128;
    b 湖南农业大学 湖南省植物功能成分利用协同创新中心 长沙 410128
  • 收稿日期:2016-07-27 修回日期:2016-09-01 出版日期:2017-01-25 发布日期:2016-10-09
  • 通讯作者: 程辟 E-mail:picheng55@126.com
  • 基金资助:

    国家自然科学基金(No. 31402109)资助项目.

Visible Light Promoted C-H Functionalization Reactions of Tertiary Amines

Liu Weia, Zheng Xinyua, Zeng Jianguoa,b, Cheng Pia,b   

  1. a National and Provincial Union Engineering Research Center for the Veterinary Herbal Medicine Resources and Initiative, College of Horticulture and Landscape Architecture, Hunan Agricultural University, Changsha 410128;
    b Hunan Co-innovation Center for Utilization of Botanicals Functional Ingredients, Hunan Agricultural University, Changsha 410128
  • Received:2016-07-27 Revised:2016-09-01 Online:2017-01-25 Published:2016-10-09
  • Supported by:

    Project supported by the National Natural Science Foundation of China(No. 31402109).

The tertiary amine motif is an important structure component of multitudinous natural products and drug molecules.Visible light promoted C-H functionalization of tertiary amines has recently received much attention and facilitated the synthesis of alkaloids and drug molecules.Based on photoredox catalysis,visible light is able to induce the formation of iminium cations or α-amino carbon radicals through single electron transfer process which can participate in multitudinous type of organic reactions and complete C-H functionalization of tertiary amines.In this review,the research progress of photoredox catalytic C-H func-tionalization was categorized and summarized.

Key words: tertiary amines, visible light, photoredox catalysis, C-H functionalization