Chin. J. Org. Chem. ›› 2017, Vol. 37 ›› Issue (6): 1450-1455.DOI: 10.6023/cjoc201610030 Previous Articles     Next Articles



闫小惠, 李加荣, 张奇, 史大昕   

  1. 北京理工大学化学与化工学院 北京 102488
  • 收稿日期:2016-10-18 修回日期:2017-01-18 发布日期:2017-02-17
  • 通讯作者: 史大昕

Synthesis of Nitroarenes under Microwave

Yan Xiaohui, Li Jiarong, Zhang Qi, Shi Daxin   

  1. School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 102488
  • Received:2016-10-18 Revised:2017-01-18 Published:2017-02-17
  • Contact: 10.6023/cjoc201610030

The reaction of arylboronic acids with bismuth(III) nitrate pentahydrate resulted in a series of nitroarenes when the reaction was carried out under microwave (120 ℃) for 1 min in 1,2-dichloroethane. Compared with traditional heating condition, the method of microwave condition for the preparation of nitroarenes was simple, efficient, time-saving, and of less by-products. In addition, possible free radical mechanism was proposed.

Key words: arylboronic acids, bismuth(III) nitrate pentahydrate, nitroarenes, microwave, free radical conversion