Chin. J. Org. Chem. ›› 2018, Vol. 38 ›› Issue (1): 277-280.DOI: 10.6023/cjoc201707023 Previous Articles     Next Articles

Special Issue: 庆祝吴养洁院士九十华诞专辑



郝延蔚a,b, 田荣强a, 吴迪a, 段征a, Mathey Françoisa   

  1. a 郑州大学化学与分子工程学院 国际磷化学实验室 河南省有机磷功能分子国际联合实验室 郑州 450001;
    b 开封大学功能材料研究中心 河南省先进碳化硅材料重点实验室 开封 475001
  • 收稿日期:2017-07-21 修回日期:2017-09-09 发布日期:2017-09-15
  • 通讯作者: 田荣强, 段征, Mathey François;;
  • 基金资助:


Synthesis, Structure and Coordination Chemistry of an α-Iminophosphaferrocene

Hao Yanweia,b, Tian Rongqianga, Wu Dia, Duan Zhenga, Mathey Françoisa   

  1. a International Phosphorus Laboratory, International Joint Research Laboratory for Functional Organophosphorus Materials of Henan Province, College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001;
    b Key Laboratory for Advanced Silicon Carbide Materials, Research Center of Functional Materials, Kaifeng University, Kaifeng 475001
  • Received:2017-07-21 Revised:2017-09-09 Published:2017-09-15
  • Contact: 10.6023/cjoc201707023;;
  • Supported by:

    Project supported by the National Natural Science Foundation of China (Nos. 21302174, 21672193, 21272218), the Young Talent Research Fund of Zhengzhou University (No. 1621316006) and the Zhengzhou University of China.

An 2-iminophospholide 1 can be obtained via two [1,5] shifts by reaction of potassium tert-butoxide with 3,4-di- methyl-1-phenylphosphole and an imidoyl chloride. The reaction of 1 with [Cp*FeCl]n affords a 2-iminophosphaferrocene 2 which behaves as a P,N chelating ligand toward Mo(CO)4 and Rh(CO)2]+. The X-ray crystal structures of 2 and its Mo complex have been recorded.

Key words: phosphaferrocene, imine, coordination chemistry