Chin. J. Org. Chem. ›› 2018, Vol. 38 ›› Issue (1): 62-74.DOI: 10.6023/cjoc201708023 Previous Articles     Next Articles

Special Issue: 热点论文合辑 元素有机化学合辑2018-2019 有机光催化合辑



高玉珍a,b, 唐果a, 赵玉芬a   

  1. a 厦门大学化学化工学院 福建省化学生物学重点实验室 厦门 361005;
    b 中国科学院福建物质结构研究所 煤制乙二醇及相关技术重点实验室 福州 350002
  • 收稿日期:2017-08-11 修回日期:2017-08-31 发布日期:2017-09-08
  • 通讯作者: 赵玉芬
  • 基金资助:


Recent Advances of Phosphorus-Centered Radical Promoted Difunctionalization of Unsaturated Carbon-Carbon Bonds

Gao Yuzhena,b, Tang Guoa, Zhao Yufena   

  1. a Key Laboratory for Chemical Biology of Fujian Province, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005;
    b Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002
  • Received:2017-08-11 Revised:2017-08-31 Published:2017-09-08
  • Contact: 10.6023/cjoc201708023
  • Supported by:

    Project supported by the National Natural Science Foundation of China (Nos. 21232005, 21375113), the National Basic Research Program of China (No. 2013CB910700), the Fundamental Research Funds for the Central Universities (No. 20720160030), the National Postdoctoral Program for Innovative Talents (No. BX201700244).

The scientists have been working on developing more efficient and green ways to synthesize organophosphorus compounds as they have broad utilities such as reagents for chemical reactions, photovoltaic materials, flame retardants, biologically active molecules and so on. The difunctionalization reactions between P-center radicals and unsaturated compounds provide powerful methods for the synthesis of organophosphorus compounds in least and concise steps. This review will summarize the recent development in this area on the basis of different types of P-centered radical initiators.

Key words: phosphorus-centered radical, difunctionalization, unsaturated compounds