Chin. J. Org. Chem. ›› 2018, Vol. 38 ›› Issue (2): 401-415.DOI: 10.6023/cjoc201708034 Previous Articles     Next Articles

Reviews

1,1-二溴-1-烯烃在有机合成中的研究进展

赵明, 纪原   

  1. 中国矿业大学化工学院 徐州 221116
  • 收稿日期:2017-08-06 修回日期:2017-09-10 出版日期:2018-02-25 发布日期:2017-09-19
  • 通讯作者: 赵明 E-mail:ming815zhao@163.com
  • 基金资助:

    中央高校基本科研业务费(No.2015QNA22)、江苏省自然科学基金(No.BK20160254)资助项目.

Progress on Synthetic Applications of 1,1-Dibromo-1-alkenes

Zhao Ming, Ji Yuan   

  1. School of Chemical Engineering, China University of Mining and Technology, Xuzhou 221116
  • Received:2017-08-06 Revised:2017-09-10 Online:2018-02-25 Published:2017-09-19
  • Contact: 10.6023/cjoc201708034 E-mail:ming815zhao@163.com
  • Supported by:

    Project supported by the Fundamental Research Funds for the Central Universities (No. 2015QNA22) and the Natural Science Foundation of Jiangsu Province (No. BK20160254).

As one type of organic synthetic materials and intermediates, 1, 1-dibromo-1-alkenes have been widely researched in C-C, C-N, C-O, C-P, and C-S bond formations. The couple of C-Br bonds in the molecule makes it reactive to afford bromoalkenes, bromoalkynes, terminal alkynes, and to prepare poly-substituted alkenes, fused aromatic rings and internal alkynes through coupling reactions. Various organic reactions with 1, 1-dibromo-1-alkenes as the starting materials are mainly reviewed.

Key words: 1,1-dibromo-1-alkene, C-Br bond, cross coupling, alkenes, fused aromatic compounds