Chin. J. Org. Chem. ›› 2019, Vol. 39 ›› Issue (5): 1424-1428.DOI: 10.6023/cjoc201812007 Previous Articles     Next Articles

Articles

通过电化学脱氢N—N偶联合成四取代肼化合物

冯恩祺, 侯中伟, 徐海超   

  1. 厦门大学化学化工学院 厦门 361005
  • 收稿日期:2018-12-04 修回日期:2018-12-27 出版日期:2019-05-25 发布日期:2019-01-18
  • 通讯作者: 徐海超 E-mail:haichao.xu@xmu.edu.cn
  • 基金资助:

    国家自然科学基金(No.21672178)、国家基础科学人才培养(No.J131002)资助项目.

Electrochemical Synthesis of Tetrasubstituted Hydrazines by Dehydrogenative N-N Bond Formation

Feng Enqi, Hou Zhongwei, Xu Haichao   

  1. College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005
  • Received:2018-12-04 Revised:2018-12-27 Online:2019-05-25 Published:2019-01-18
  • Contact: 10.6023/cjoc201812007 E-mail:haichao.xu@xmu.edu.cn
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No. 21672178) and the National Foundation for Fostering Talents in Basic Science (No. J1310024).

An electrochemical synthesis of tetrasubstituted hydrazines through dehydrogenative dimerization of secondary amines has been developed. The reactions are conducted in a simple undivided cell with constant current. The use of electricity to promote the reactions obviates the need for transition metal catalysts and oxidizing reagents, providing an efficient and sustainable access to tetrasubstituted hydrazines with diverse electronic properties.

Key words: organic electrosynthesis, anodic oxidation, dehydrogenative coupling, tetrasubstituted hydrazines