Chinese Journal of Organic Chemistry ›› 2020, Vol. 40 ›› Issue (2): 351-363.DOI: 10.6023/cjoc201909022 Previous Articles     Next Articles


蔡金芳a, 江华a,b, 崔志华a,b, 陈维国a,b   

  1. a 浙江理工大学 生态染整技术教育部工程研究中心 杭州 310018;
    b 浙江理工大学 先进纺织材料与制备技术教育部重点实验室 杭州 310018
  • 收稿日期:2019-09-15 修回日期:2019-10-14 发布日期:2019-11-01
  • 通讯作者: 江华
  • 基金资助:

Research Progress in Design, Synthesis and Application for Quinoidal Heterocyclic Compounds

Cai Jinfanga, Jiang Huaa,b, Cui Zhihuaa,b, Chen Weiguoa,b   

  1. a Engineering Research Center for Eco-dyeing and Finishing of Textiles, Ministry of Education, Zhejiang Sci-Tech University, Hangzhou 310018;
    b Key Laboratory of Advanced Textile Materials and Manufacturing Technology, Ministry of Education, Hangzhou 310018
  • Received:2019-09-15 Revised:2019-10-14 Published:2019-11-01
  • Supported by:
    Project supported by the Public Welfare Technology Research Project of Zhejiang Province (No. LGG18B060003), the National Natural Science Foundation of China (Nos. 21808210, 51673176) and the Fundamental Research Funds of Zhejiang Sci-Tech University (No. 2019Q018).

Quinoidal heterocyclic (thiophene, pyrrole, furan, etc.) molecules have the characteristics of rigid backbone, low highest occupied molecular orbital (HOMO)/lowest unoccupied molecular orbital (LUMO) level, narrow band gap and high molar extinction coefficient, and so on. Because of their planar structures, quinoidal molecules usually have strong intermolecular charge transfer ability due to the strong intermolecular interaction. Up to now, quinoidal heterocyclic molecules have become a research hotspot in the field of organic semiconductor materials, especially in the field of organic field effect transistors. According to the structural features of quinoidal heterocyclic molecules and the classification basis of terminal groups, the research progress of quinoidal heterocyclic compounds in molecular design, synthesis and application in recent years is reviewed, and the development of quinoidal heterocyclic molecules is prospected.

Key words: quinoidal heterocyclic compound, design and synthesis, property and application, organic semiconductor material, organic field effect transistors