Chinese Journal of Organic Chemistry ›› 2021, Vol. 41 ›› Issue (8): 3235-3241.DOI: 10.6023/cjoc202101047 Previous Articles     Next Articles



李萍, 周志强, 杨帆, 徐瑶, 张小祥*()   

  1. 南京林业大学化学工程学院 江苏省林业资源高效加工利用协同创新中心 南京210037
  • 收稿日期:2021-01-27 修回日期:2021-04-10 发布日期:2021-05-08
  • 通讯作者: 张小祥
  • 基金资助:
    国家自然科学基金(21302096); 江苏省自然科学基金(BK20171449); 国家一流学科资助项目

Palladium-Catalyzed Synthesis of 1H-Indol-3-yl Acrylates from 2-Alkynyl Arylazides and Acrylic Acids

Ping Li, Zhiqiang Zhou, Fan Yang, Yao Xu, Xiaoxiang Zhang()   

  1. Jiansu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037
  • Received:2021-01-27 Revised:2021-04-10 Published:2021-05-08
  • Contact: Xiaoxiang Zhang
  • Supported by:
    National Natural Science Foundation of China(21302096); Natural Science Foundation of Jiangsu Province(BK20171449); National First-class Disciplines(PNFD)

A novel method to prepare 1H-indol-3-yl acrylates from 2-alkynyl arylazides with acrylic acids catalyzed by Pd has been described. A variety of 1H-indol-3-yl acrylate derivatives were prepared under mild reaction conditions.

Key words: Pd-catalysis, α-imino palladium carbene, indole-3-acrylate, acrylic acid