Chinese Journal of Organic Chemistry ›› 2021, Vol. 41 ›› Issue (8): 2990-3001.DOI: 10.6023/cjoc202103013 Previous Articles     Next Articles



罗欢欢, 裴娜, 张敬*()   

  1. 武汉大学高等研究院 武汉 430000
  • 收稿日期:2021-03-06 修回日期:2021-04-02 发布日期:2021-05-08
  • 通讯作者: 张敬
  • 基金资助:

Advances in Nitrogen-Directed Aromatic Compound ortho-C—H Bond Borylation Catalyzed by Transition Metals

Huanhuan Luo, Na Pei, Jing Zhang()   

  1. Institute for Advanced Studies, Wuhan University, Wuhan 430000
  • Received:2021-03-06 Revised:2021-04-02 Published:2021-05-08
  • Contact: Jing Zhang
  • Supported by:
    Fundamental Research Funds for the Central Universities(2042019kf0008)

Aromatic boron compounds have been widely used in synthetic chemistry, materials and medicinals, and developing new methods for their synthesis has been a hot topic. Directing groups assisted C—H bond borylation catalyzed by transition metal has significant advantages in step-economy, substrates diversity and high regio-selectivity. The borylation of nitrogen-based substrates has attracted interest from researchers, because four-coordinated organoboron compounds chelated by N,C are important photoelectric materials. In this paper, the preparation of aromatic boron compounds from ortho-C—H bond borylation catalyzed by Ir, Rh, Ru, Pd assisting by directing groups containing nitrogen atoms is summarized.

Key words: ortho-C—H activation, borylation, nitrogen-directed, transition metal catalyze