Chinese Journal of Organic Chemistry ›› 2023, Vol. 43 ›› Issue (9): 3146-3166.DOI: 10.6023/cjoc202308001 Previous Articles     Next Articles

过渡金属催化不对称C—H硼化反应研究进展

王文芳*()   

  1. 西北民族大学化工学院 环境友好复合材料国家民委重点实验室 甘肃省高校环境友好复合材料及生物质利用重点实验室 甘肃省生物质功能复合材料工程研究中心 兰州 730000
  • 收稿日期:2023-08-01 修回日期:2023-09-12 发布日期:2023-09-21
  • 基金资助:
    中央高校基本科研业务费(31920190079); 西北民族大学科研(xbmuyjrc 201905)

Recent Progress in Transition-Metal-Catalyzed Asymmetric C—H Borylation

Wenfang Wang()   

  1. Gansu Provincial Biomass Function Composites Engineering Research Center, Key Laboratory for Utility of Environment-Friendly Composite Materials and Biomass in University of Gansu Province, Key Laboratory of Environment-Friendly Composite Materials of the State Ethnic Affairs Commission, College of Chemical Engineering, Northwest Minzu University, Lanzhou 730000
  • Received:2023-08-01 Revised:2023-09-12 Published:2023-09-21
  • Contact: E-mail: wangwenfang@xbmu.edu.cn
  • Supported by:
    Fundamental Research Funds for the Central Universities(31920190079); Scientific Research Foundation of Northwest Minzu University(xbmuyjrc 201905)

Transition-metal-catalyzed asymmetric C—H borylation is one of the most powerful strategies for the construction of chiral organoborate compounds, which has attracted extensive attention in the fields of synthetic chemistry, medicinal chemistry and materials science due to its atom- and step-economy. The design and synthesis of novel chiral ligands are essential for the success of asymmetric C—H borylation. Based on the design and development of chiral ligands, the recent progress of transition-metal-catalyzed asymmetric C(sp2)—H and C(sp3)—H borylation reactions is summarized.

Key words: asymmetric C—H borylation, chiral ligand, transition metal complex