Chinese Journal of Organic Chemistry ›› 2021, Vol. 41 ›› Issue (10): 3903-3913.DOI: 10.6023/cjoc202106004 Previous Articles     Next Articles

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有机膦氧化还原催化反应研究进展

蔡卫, 黄有*()   

  1. 南开大学化学学院 元素有机化学国家重点实验室 天津 300071
  • 收稿日期:2021-06-02 修回日期:2021-07-01 发布日期:2021-07-12
  • 通讯作者: 黄有
  • 基金资助:
    国家自然科学基金(21871148); 国家自然科学基金(21672109)

Advances in Organophosphorus Redox Catalysis

Wei Cai, You Huang()   

  1. State Key Laboratory and Institute of Elemento-organic Chemistry, College of Chemistry, Nankai University, Tianjin 300071
  • Received:2021-06-02 Revised:2021-07-01 Published:2021-07-12
  • Contact: You Huang
  • Supported by:
    National Natural Science Foundation of China(21871148); National Natural Science Foundation of China(21672109)

Organophosphorus reagents play very important role in organic synthesis. The development of Wittig reaction, Staudinger reaction, Appel reaction and Mitsunobu reaction mediated by phosphine compounds is of great significance in scientific research and industrial production. In recent decades, the research on the design of P(III)/P(V) redox catalysis and catalysts to realize the catalytic mode of these reactions, and avoiding the production of stoichiometric R3P=O has developed rapidly. This review introduces the research progress of the catalytic process of each reaction in turn. The future research direction in this field about the reactions involving stoichiometric R3P=O is prospected.

Key words: Wittig reaction, Staudinger reaction, Appel reaction, Mitsunobu reaction, phosphine catalysis, P(III)/P(V) redox catalysis