Synthesis and structure of (t-BuCp)2YbCl·THF

Abstract

The title compound was prepared by reaction of YbCl3 and two equiv sodium tert-butylcyclopentadienide in THF, and the structure was determine by x-ray crystallog. The two ring centroids of the tert-butylcyclopentadienyl rings, the chlorine atom, and the oxygen atom of the THF form a distorted tetrahedron around the central ion of ytterbium. The average Yb-C bond length is 0.2628(10) nm, with Yb-Cl and Yb-O distances of 0.2537(3) nm and 0.2333(6) nm, resp.

Key words: INFRARED SPECTROPHOTOMETRY, SODIUM COMPOUNDS, CHLORIDE, X-RAY DIFFRACTION ANALYSIS, TETRAHYDROFURAN, CRYSTAL STRUCTURE, PROTON MAGNETIC RESONANCE SPECTROMETRY, CHLORIDE, CYCLOPENTADIENE P, CYCLOPENTADIENE P

CLC Number:

O611.662

Cite this article

GUAN JINGWEN;LIN YONGHUA;SHEN QI. Synthesis and structure of (t-BuCp)2YbCl·THF[J]. Chin. J. Org. Chem., 1991, 11(3): 261-264.

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(t-BuCp)2YbCl·THF的合成和晶体结构