Chin. J. Org. Chem. ›› 1993, Vol. 13 ›› Issue (1): 57-60. Previous Articles     Next Articles

Original Articles

胆紫素的形成和八乙基卟啉的光氧化

李红;侯原军;马金石;梁晓光   

  1. 中国科学院感光化学研究所
  • 发布日期:1993-02-25

Formation of biliviolin and photooxygenation of octaethylporphyrin

LI HONG;HOU YUANJUN;MA JINSHI;LIANG XIAOGUANG   

  • Published:1993-02-25

Octaethylporphryrin-magnesium (MgOEP)was photooxygenated to yield a brown product-1-formyloctaethylbiliverdin 1 which could coordinate with Zn+ and then be purified through chromatography.1 was oxidated byb silver nitrate to give 15-oxo-19-for-myloctaethylbilivionlin2.

Key words: SILVER NITRATE, PHOTOOXIDATION, MAGNESIUM COMPLEX, CHOLEHEMATIN (=PHYLLOERYTHRIN, BILIPURPURIN), PORPHYRIN

CLC Number: