Chin. J. Org. Chem. ›› 1993, Vol. 13 ›› Issue (6): 633-637. Previous Articles    

Original Articles

具有共轭体系的酮类烯醇硅醚与全氟碘代烷的反应

黄维垣;吴永明   

  1. 中国科学院上海有机化学研究所.上海(200032)
  • 发布日期:1993-12-25

The reaction of silyl enol ether of conjugated ketones with perfluoroalkyl iodide

Huang Weiyuan;Wu Yongming   

  1. Shanghai Inst Organ Chem., CAS.Shanghai(200032)
  • Published:1993-12-25

The reaction of silyl enol ether of acetophenone 1 and methyl vinylketone 5 with perfluoroalkyl iodide 2a-2c initiated with sodium dithionite was shown to give the products 3a-3c and a mixture of 6a- 6c, 7a-7c and 8a-8c respectively. Possible mechanisms of forming these products were proposed.

Key words: ALKYLATION, KETONE

CLC Number: