Research on the cyclopropanation of the enoxysilane by  use of ultrasound irradiation

Chin. J. Org. Chem. ›› 1998, Vol. 18 ›› Issue (6): 550-555. Previous Articles Next Articles

Original Articles

超声波作用下的烯醇硅醚环丙化反应的研究

孙海洲;李基森

中国科学院上海有机化学研究所.上海(200032)

发布日期:1998-12-25

Research on the cyclopropanation of the enoxysilane by use of ultrasound irradiation

Sun Haizhou;Li Jisen

Shanghai Inst Organ Chem., CAS.Shanghai(200032)

Published:1998-12-25

Abstract

The cyclopropanation of the enoxysilane by the ultrasound- accelerated Simmons-Smith reaction was studied intensively. Experimental results reveal that ultrasound and copper(Ⅰ) chloride can efficiently activate the zinc dust, and result in 56～78% yields of cyclopropane products. Then, the effects of the intensity of ultrasonic waves, the temperature, the solvent and the reaction time were examined.

Key words: ULTRASONIC WAVES, SILOXANE, ENOLS P, ACTIVATION, CYCLOPROPANE P, REACTION CONDITION, ORGANO SILICON COMPOUNDS, ZINC POWDER, CUPROUS CHLORIDE, ETHER

CLC Number:

O621

Cite this article

Sun Haizhou;Li Jisen. Research on the cyclopropanation of the enoxysilane by use of ultrasound irradiation[J]. Chin. J. Org. Chem., 1998, 18(6): 550-555.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

[1]	Yatong Fu, Chaofan Sun, Dan Zhang, Chengguo Jin, Juyou Lu. Recent Progress in B—H Bond Functionalization of nido-Carboranes [J]. Chinese Journal of Organic Chemistry, 2024, 44(2): 438-447.
[2]	Xiaoyang Gao, Ruirui Zhai, Xun Chen, Shuojin Wang. Recent Progress in C—H Bond Activation Reaction with Vinylene Carbonate [J]. Chinese Journal of Organic Chemistry, 2023, 43(9): 3119-3134.
[3]	Lingna Wang, Xiaoqing Liu, Gang Lin, Hongying Jin, Minjun Jiao, Xuefen Liu, Shuping Luo. Photocatalytic Activation of C(sp³)—H Bonds to Form C—S Bonds Catalyzed by (Oxybis(4,1-phenylene))bis(phenylmethanone) [J]. Chinese Journal of Organic Chemistry, 2023, 43(8): 2848-2854.
[4]	Yingjie Liu, Gangqing Shi, Ge Chou, Xin Zhang, Dongxue Song, Ning Chen, Miao Yu, Ying Xu. Progress of α-Position Functionalization of Ethers under Photo/Electrocatalysis [J]. Chinese Journal of Organic Chemistry, 2023, 43(8): 2664-2681.
[5]	Sifan Dong, Haolong Li, Yuan Qin, Shiming Fan, Shouxin Liu. Research Progress of Amino Acids as Transient Directing Groups in C—H Bond Activation Reactions [J]. Chinese Journal of Organic Chemistry, 2023, 43(7): 2351-2367.
[6]	Xiaojing Hu, Feixiang Guo, Runqing Zhu, Bingqi Zhou, Tao Zhang, Lizhen Fang. Synthesis of p-Alkoxy Phenol and Its Application after Dearomatization [J]. Chinese Journal of Organic Chemistry, 2023, 43(6): 2239-2244.
[7]	Xiantao Ma, Xiaoyu Yan, Yingying Zhu, Shuanglin Niu, Yuxuan Wang, Chao Yuan. Water-Promoted Green Synthesis of Heteroaryl Thioether [J]. Chinese Journal of Organic Chemistry, 2023, 43(6): 2136-2142.
[8]	Gefei Li, Jie Jing, Zhenyang Luo, Juan Mo, Decai Xiong, Xinshan Ye. Recent Advances in Protection-Free Glycosylations [J]. Chinese Journal of Organic Chemistry, 2023, 43(6): 1991-2001.
[9]	Hairui Jia, Zaozao Qiu. Recent Advances in Transition Metal-Catalyzed B—H Bond Activation for Synthesis of o-Carborane Derivatives with B—Heteroatom Bond [J]. Chinese Journal of Organic Chemistry, 2023, 43(3): 1045-1068.
[10]	Kongchuan Wu, Kaihong Lu, Jianbin Lin, Huijun Zhang. Research Progress in Ortho-C—H Bond Functionalization of Rylene Diimides [J]. Chinese Journal of Organic Chemistry, 2023, 43(3): 1000-1011.
[11]	Shuyong Song, Senmiao Xu. Recent Progress in Selective C-F Bond Activation of Trifluoromethyl Alkenes [J]. Chinese Journal of Organic Chemistry, 2023, 43(2): 411-425.
[12]	Fang Wang, Lei Wang. Recent Advances in Functionalization of Aromatic C(sp²)—H Bonds Based on N-Nitroso Direction [J]. Chinese Journal of Organic Chemistry, 2023, 43(12): 4157-4167.
[13]	Meijiao Sun, Jing Tan, Yu Tan, Jinsong Peng, Chunxia Chen. Pd-Catalyzed C(2)—H Arylation of 3-(2-Aminopyrimidin-4-yl)indoles [J]. Chinese Journal of Organic Chemistry, 2023, 43(11): 3945-3959.
[14]	Weilu Zhang, Shaowei Chen, Xiao Shen. Nickel-Catalyzed [4＋2] Cyclization of Benzosilacyclobutenes and Acylsilanes [J]. Chinese Journal of Organic Chemistry, 2023, 43(10): 3635-3643.
[15]	Hao Zhang, Qingbin Zhao, Zhongrui Ruan, Zhenxing Liu. Recent Development of SuFEx Reaction between Silyl Ethers and Sulfur(VI) Fluoride Compounds [J]. Chinese Journal of Organic Chemistry, 2023, 43(10): 3569-3579.

超声波作用下的烯醇硅醚环丙化反应的研究

Research on the cyclopropanation of the enoxysilane by use of ultrasound irradiation

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments