Synthesis of Nitroarenes under Microwave

doi:10.6023/cjoc201610030

Chin. J. Org. Chem. ›› 2017, Vol. 37 ›› Issue (6): 1450-1455.DOI: 10.6023/cjoc201610030 Previous Articles Next Articles

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微波促进下芳基硼酸合成芳香族硝基化合物的研究

闫小惠, 李加荣, 张奇, 史大昕

北京理工大学化学与化工学院北京 102488

收稿日期:2016-10-18 修回日期:2017-01-18 发布日期:2017-02-17
通讯作者: 史大昕 E-mail:shidaxin@bit.edu.cn

Synthesis of Nitroarenes under Microwave

Yan Xiaohui, Li Jiarong, Zhang Qi, Shi Daxin

School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 102488

Received:2016-10-18 Revised:2017-01-18 Published:2017-02-17
Contact: 10.6023/cjoc201610030 E-mail:shidaxin@bit.edu.cn

1. Synthesis of Nitroarenes under Microwave.PDF(522KB)

Abstract

The reaction of arylboronic acids with bismuth(III) nitrate pentahydrate resulted in a series of nitroarenes when the reaction was carried out under microwave (120 ℃) for 1 min in 1,2-dichloroethane. Compared with traditional heating condition, the method of microwave condition for the preparation of nitroarenes was simple, efficient, time-saving, and of less by-products. In addition, possible free radical mechanism was proposed.

Key words: arylboronic acids, bismuth(III) nitrate pentahydrate, nitroarenes, microwave, free radical conversion

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Yan Xiaohui, Li Jiarong, Zhang Qi, Shi Daxin. Synthesis of Nitroarenes under Microwave[J]. Chin. J. Org. Chem., 2017, 37(6): 1450-1455.

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微波促进下芳基硼酸合成芳香族硝基化合物的研究

Synthesis of Nitroarenes under Microwave

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