镎和钚与环境中无机阴离子的配位化学研究进展

doi:10.6023/A21080380

化学学报 ›› 2021, Vol. 79 ›› Issue (12): 1415-1424.DOI: 10.6023/A21080380 上一篇下一篇

综述

镎和钚与环境中无机阴离子的配位化学研究进展

董雪^a, 曹鸿^a, 徐雷^a^,^b, 王志鹏^a^,^*(), 陈靖^a, 徐超^a^,^*()

a 清华大学核能与新能源技术研究院北京 100084
b 浙江大学原子核农业科学研究所杭州 310058

投稿日期:2021-08-13 发布日期:2021-10-08
通讯作者: 王志鹏, 徐超

作者简介:

董雪, 男, 博士研究生. 2018年7月毕业于西南科技大学国防科技学院, 获学士学位. 目前就读于清华大学核能与新能源技术研究院, 主要从事核废物处理中超铀元素的化学行为和分离机制研究.

王志鹏, 男, 助理研究员. 2019年于四川大学获放射化学专业博士学位. 2019~2021年在清华大学核能与新能源技术研究院开展博士后研究. 2021年8月起任职助理研究员. 主要从事于核燃料循环相关的分离化学、氧化还原化学和配位化学研究.

徐超, 男, 清华大学核能与新能源技术研究院长聘副教授. 2009年于北京大学获理学博士学位, 同年进入清华大学核能与新能源技术研究院工作至今. 中国化学会核化学与放射化学分会理事会副秘书长, 中国核学会锕系物理与化学分会理事. 主要研究领域包括放射性废物高效分离和处理技术, 锕系及镧系离子配位化学等.

基金资助:
国家自然科学基金(21822606); 国家自然科学基金(21790372)

Advances in Environmental Coordination Chemistry of Np and Pu with Inorganic Anions in Aqueous Solution

Xue Dong^a, Hong Cao^a, Lei Xu^a^,^b, Zhipeng Wang^a(), Jing Chen^a, Chao Xu^a()

a Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084
b Institute of Nuclear-Agricultural Sciences, Zhejiang University, Hangzhou 310058

Received:2021-08-13 Published:2021-10-08
Contact: Zhipeng Wang, Chao Xu
Supported by:
National Natural Science Foundation of China(21822606); National Natural Science Foundation of China(21790372)

文章分享

摘要/Abstract

镎(Np)和钚(Pu)是核能领域两种重要的锕系元素, 其在水溶液中的配位化学对于了解和控制其在水环境中的种态分布和迁移行为具有重要意义. Review了近十几年来国内外Np和Pu与环境中常见无机阴离子在水溶液中的配位化学研究进展, 重点阐述了不同价态Np/Pu离子与OH^–、 $CO_3^{2-}$、 $SO_4^{2-}$、Cl^–、 $NO_3^-$、F^–、 $PO_4^{3-}$等阴离子之间形成的配位物种和配位热力学信息, 并对该领域存在的关键科学问题和未来发展方向进行了分析和展望.

关键词: 镎, 钚, 环境, 无机阴离子, 配位化学, 热力学

Neptunium (Np) and plutonium (Pu) are two important actinides in nuclear industry. They can be generated through neutron capture of uranium (U) in reactors or decay from other transuranic elements. Representative isotopes of Np and Pu such as ²³⁷Np and ²³⁹Pu have long half-lives and possess high radiotoxicity, therefore may impose great hazard to biological system if they are released into the environment. The rich redox chemistry of Np and Pu further adds complexity of their chemical behavior in the environment. The coordination chemistry of Np and Pu in aqueous solution is of great significance to help understand and control their speciation distribution and migration behaviors in aqua environment. This article reviews the advances in coordination chemistry of Np and Pu with several common inorganic anions (OH^–, $CO_3^{2-}$, $SO_4^{2-}$, Cl^–, $NO_3^-$, F^–, $PO_4^{3-}$) in aqueous solution, especially the speciation and coordination thermodynamics between Np/Pu in different oxidation states and these anions. In general, Np and Pu ions in the same oxidation state exhibit similar coordination behavior (species, structure, stability constants, etc.) when coordinating with the same anion. The coordination strength for Np/Pu ions in different oxidation states with the same anion ligand is roughly in the order of IV>III, VI>V. For the coordination of Np/Pu ions with different anions, the strength sequences are OH^–>F^–> ${H_2}PO_4^-$> $NO_3^-$>Cl^– for monovalent anions and $CO_3^{2-}$> $HPO_4^{2-}$> $SO_4^{2-}$ for divalent anions. Factors such as instability of Np/Pu ions in some oxidation states, weak complexation, and low solubility of the complexes in the aqueous solution cause difficulties in obtaining precise and reliable coordination parameters for these ions experimentally. Moreover, the coordination parameters determined by different methods may vary with each other. To obtain more reliable parameters for the coordination of Np/Pu ions with these anions in the future, the use of more advanced characterization methods and the assistance of theoretical computation may provide strong support.

Key words: neptunium, plutonium, environment, inorganic anion, coordination chemistry, thermodynamics

引用此文

董雪, 曹鸿, 徐雷, 王志鹏, 陈靖, 徐超. 镎和钚与环境中无机阴离子的配位化学研究进展[J]. 化学学报, 2021, 79(12): 1415-1424.

Xue Dong, Hong Cao, Lei Xu, Zhipeng Wang, Jing Chen, Chao Xu. Advances in Environmental Coordination Chemistry of Np and Pu with Inorganic Anions in Aqueous Solution[J]. Acta Chimica Sinica, 2021, 79(12): 1415-1424.

导出引用 EndNote|Reference Manager|ProCite|BibTeX|RefWorks

分享此文

图/表 10

	log β⁰₁	log β⁰₂	log β⁰₃	log β⁰₄	Ref.
Np(IV)	0.55±0.20	0.35±0.30		–8.30±1.10	[17]
Np(IV)	0.5±0.2	0.3±0.3	–2.8±1.0	–8.3±1.1	[16]
Pu(IV)	0.60±0.20	0.60±0.30	–2.30±0.40	–8.50±0.50	[17]
Pu(IV)	0.0±0.2	–1.2±0.6	–3.1±0.9		[18]

表1. Np(IV)和Pu(IV)离子的标准水解常数(I=0, T=25 ℃)a

Table 1. Hydrolysis constants of tetravalent Np/Pu (I=0, T=25 ℃)

图1. 水溶液中各氧化态Pu随时间变化的分布曲线[18]

Figure 1. Typical examples of plutonium oxidation state distribution curves in aqueous as a function of time

	Species	I/(mol•L^–1)	log β	Ref.
Np(IV)	[Np(CO₃)₂(OH)₂]^2–	0	46.4±0.5	[22]
	[NpCO₃(OH)₄]^2–	0	50.5±0.5	[22]
	[Np(CO₃)₂(OH)₄]^4–	0	47.4±0.5	[23]
Pu(IV)	[Pu(CO₃)₂(OH)₄]^4–	0.1	49.7±0.5	[24]
	[Pu(CO₃)₂(OH)₂]^2–	0	44.8	[22]
	[Pu(CO₃)₂(OH)₂]^2–	0.1	44.2±0.6	[24]

表2. Np(IV)、Pu(IV)离子与 $CO_3^{2-}$配位常数比较(T=295±3 K)

Table 2. Comparison of the logarithm of coordination constants for tetravalent Np/Pu with $CO_3^{2-}$ at T=295±3 K

	log β	∆G⁰/(kJ•mol^–1)	∆H⁰/(kJ•mol^–1)	∆S⁰/(J•k^–1•mol^–1)
[PuSO₄]²⁺	2.71±0.05	–15.5	11.2	89.6
Pu(SO₄)₂	4.59±0.04	–26.2	5.1	104.8

表3. Pu(IV)与 $SO_4^{2-}$形成1∶1和1∶2型配合物的热力学参数[26]

Table 3. Thermodynamic parameters for the complexation of Pu(IV) with $SO_4^{2-}$

	log *β_n	∆G_n⁰/(kJ•mol^–1)	∆H_n^b/(kJ•mol^–1)	∆S_n^b/(J•K^–1•mol^–1)
NpO₂(OH)	–9.01±0.07	51.3±0.5	31.6±0.6	–66±3
[NpO₂(OH)₂]^–	–18.95±0.07	28.6±0.3	39.7±0.5	47.5±0.5

表4. Np(V)水解的热力学参数(T=25 ℃)[35]

Table 4. Thermodynamic parameters for Np(V) hydrolysis (T=25 ℃)

	Method	log β⁰₁	log β⁰₂	log β⁰₃	Ref.
Np(V)	光谱法	4.92±0.06	6.53±0.06	5.50±0.15	[14, 17]
Np(V)	CE-ICP-MS	4.88±0.12	6.27±0.11	5.64±0.15	[34]
Pu(V)	光谱法	4.95±0.10		5.03±0.95	[17]
Pu(V)	CE-ICP-MS	4.95±0.01	6.34±0.10	5.61±0.16	[34]

表5. 五价锕系离子Np(V)、Pu(V)与 $CO_3^{2-}$的配位常数(T=25 °C)

Table 5. Stability constants for pentavalent Np/Pu with $CO_3^{2-}$ at T=25 °C

图2. Np(V)与 $SO_4^{2-}$配位反应的近红外吸收光谱图

Figure 2. Representative spectrophotometric titrations of Np(V)/sulfate complexation I=1.0 mol/L NaClO4/Na2SO4. Upper figures are normalized absorption spectra. Titrant: 0.5 mol/L Na2SO4. Initial solution in cuvette: 2.50 mL; 10 ℃: CNpClO4/CHClO4=5.124×10–3 mol•L–1/1.0×10–6 mol•L–1; 70 ℃: CNpClO4/CHClO4=5.0×10–3 mol•L–1/1.0×10–6 mol•L–1. Lower figures are calculated molar absorptivity of $NpO_2^+$ and [NpO2SO4]–[40]

	log β	∆H/(kJ•mol^–1)	∆S/(J•k^–1•mol^–1)	Ref.
NpO₂F	1.42±0.10	20.8	96.9	[38]
	1.26±0.15	7.3±3.6	48±11	[45]
	1.25±0.05	8.1±1.0	51±5	[46]
[NpO₂F₂]^–	1.79±0.20	17.2±6.0	90±18	[45]
[NpO₂F₂]^–	1.77±0.09	14.2±3.1	82±12	[46]

表6. $NpO_2^+$与F–在水溶液中配位的热力学参数(T=25 ℃, I=1.0 mol/L)

Table 6. Thermodynamic parameters for the complexation of $NpO_2^+$ with F– in aqueous solution (T=25 °C, I=1.0 mol/L)

图3. Np在–0.8 V≤EH≤+1.0 V, 10≤pH≤14范围内的优势区相图[47]

Figure 3. Predominance diagrams of Np for –0.8 V≤EH≤+1.0 V and 10≤pH≤14

图4. Pu(VI)在不同pH条件下水解的近红外吸收光谱图(CPu(VI)=50 µmol/L, I=0.01 mol/L NaClO4)[50]

Figure 4. Representative near infrared absorption spectra of Pu(VI) hydrolysis species under different pH conditions (CPu(VI)=50 µmol/L, I=0.01 mol/L NaClO4)

参考文献 63

[1]	Altmaier, M.; Gaona, X.; Fanghaenel, T. Chem. Rev. 2013, 113, 901. doi: 10.1021/cr300379w pmid: 23369090
[2]	Magill, J.; Berthou, V.; Haas, D.; Galy, J.; Schenkel, R. Nucl. Energy 2003, 42, 263.
[3]	Maher, K.; Bargar, J. R.; Brown, G. E. Inorg. Chem. 2013, 52, 3510. doi: 10.1021/ic301686d pmid: 23137032
[4]	Wang, Z. P.; Pu, N.; Tian, Y.; Xu, C.; Wang, F.; Liu, Y.; Zhang, L. R.; Chen, J.; Ding, S. D. Inorg. Chem. 2019, 58, 5457. doi: 10.1021/acs.inorgchem.8b01635
[5]	Neck, V.; Altmaier, M.; Fanghänelab, T. C. R. Chim. 2007, 10, 959. doi: 10.1016/j.crci.2007.02.011
[6]	Ikeda-Ohno, A.; Hennig, C.; Rossberg, A.; Funke, H.; Scheinost, A. C.; Bernhard, G.; Yaita, T. Inorg. Chem. 2008, 47, 8294. doi: 10.1021/ic8009095 pmid: 18698766
[7]	Knope, K. E.; Soderholm, L. Chem. Rev. 2013, 113, 944. doi: 10.1021/cr300212f
[8]	Altmaier, M.; Vercouter, T.; Poinssot, C.; Geckeis, H. Radionuclide Behaviour in the Natural Environment. Science, Implications and Lessons for the Nuclear Industry, Woodhead Publishing, Cambridge, 2012.
[9]	Shilov, V. P.; Gogolev, A. V.; Fedoseev, A. M.; Ershov, B. G. Radiochemistry 2012, 54, 22.
[10]	Choppin, G. R. Radiochim. Acta 1983, 32, 43. doi: 10.1524/ract.1983.32.13.43
[11]	Mefod'Eva, M. P.; Krot, N. N.; Afanas'Eva, T. V.; Gel'Man, A. D. Bull. Acad. Sci. USSR, Div. Chem. Sci. 1974, 23, 2285. doi: 10.1007/BF00921308
[12]	Cho, H. R.; Youn, Y. S.; Jung, E. C.; Cha, W. Dalton Trans. 2016, 45, 19449. doi: 10.1039/C6DT03992H
[13]	Thomas, V.; Vitorge, P.; Amekraz, B.; Giffaut, E.; Hubert, S.; Moulin, C. Inorg. Chem. 2005, 44, 5833. doi: 10.1021/ic050214n
[14]	Lemire, R. J.; Fuger, J.; Nitsche, H.; Potter, P. E.; Rand, M. H.; Rydberg, J.; Spahiu, K.; Sullivan, J. C.; Ullman, W. J.; Vitorge, P.; Wanner, H. Chemical Thermodynamics of Neptunium and Plutonium, Elsevier, North Holland, Amsterdam, 2001.
[15]	Fujiwara, K.; Kohara, Y. Radiochim. Acta 2008, 96, 613. doi: 10.1524/ract.2008.1544
[16]	Neck, V.; Kim, J. I.; Seidelc, B. S.; Marquardt, C. M.; Dardenne, K.; Jensen, M. P.; Hauser, W. Radiochim. Acta 2001, 89, 439. doi: 10.1524/ract.2001.89.7.439
[17]	Guillaumont, R.; Mompean, F. J. Update on the Chemical Thermodynamics of Uranium, Neptunium, Plutonium, Americium and Technetium, Elsevier, Amsterdam, The Netherlands, 2003.
[18]	Yun, J. I.; Cho, H. R.; Neck, V.; Altmaier, M.; Seibert, A.; Marquardt, C. M.; Walther, C.; Fanghänel, T. Radiochim. Acta 2007, 95, 89. doi: 10.1524/ract.2007.95.2.89
[19]	Walther, C.; Cho, H. R.; Marquardt, C. M.; Neck, V.; Seibert, A.; Yun, J. I.; Fanghänel, T. Radiochim. Acta 2007, 95, 7. doi: 10.1524/ract.2007.95.1.7
[20]	Silver, G. L. J. Radioanal. Nucl. Chem. 2011, 288, 89. doi: 10.1007/s10967-010-0953-2
[21]	Silver, G. L. J. Radioanal. Nucl. Chem. 2012, 291, 915. doi: 10.1007/s10967-011-1401-7
[22]	Kitamura, A.; Kohara, Y. Radiochim. Acta 2004, 92, 583. doi: 10.1524/ract.92.9.583.55002
[23]	Kitamura, A.; Kohara, Y. J. Nucl. Sci. Technol. 2002, 39, 294. doi: 10.1080/00223131.2002.10875466
[24]	Yamaguchi, T.; Sakamoto, Y.; Ohnuki, T. Radiochim. Acta 1994, 66, 9.
[25]	Clark, D. L.; Hecker, S. S.; Jarvinen, G. D.; Neu, M. P. The Chemistry of the Actinide and Transactinide Elements, Springer, Dordrecht, 2006.
[26]	Xia, Y. X.; Friese, J. I.; Moore, D. A.; Bachelor, P. P.; Rao, L. F. J. Radioanal. Nucl. Chem. 2007, 274, 79. doi: 10.1007/s10967-006-6907-z
[27]	Danesi, P. R.; Chiarizia, R.; Scibona, G.; D'Alessandro, G. J. Inorg. Nucl. Chem. 1971, 33, 3503. doi: 10.1016/0022-1902(71)80672-3
[28]	Veirs, D. K.; Smith, C. A.; Berg, J. M.; Zwick, B. D.; Marsh, S. F.; Allen, P.; Conradson, S. D. J. Alloys Compd. 1994, 213, 328.
[29]	Berg, J. M.; Veirs, D. K.; Vaughn, R. B.; Cisneros, M. R.; Smith, C. A. Appl. Spectrosc. 2000, 54, 812. doi: 10.1366/0003702001950436
[30]	Allen, P. G.; Veirs, D. K.; Conradson, S. D.; Smith, C. A.; Marsh, S. F. Inorg. Chem. 1996, 35, 2841. doi: 10.1021/ic9511231
[31]	Dacheux, N.; Thomas, A. C.; Brandel, V.; Genet, M. J. Nucl. Mater. 2000, 257, 108. doi: 10.1016/S0022-3115(98)00443-7
[32]	Brandel, V.; Dacheux, N. J. Solid State Chem. 2004, 177, 4743. doi: 10.1016/j.jssc.2004.08.009
[33]	Topin, S.; Aupiais, J. J. Environ. Radioact. 2016, 153, 237. doi: 10.1016/j.jenvrad.2015.12.016
[34]	Topin, S.; Aupiais, J.; Moisy, P. Electrophoresis 2009, 30, 1747. doi: 10.1002/elps.v30:10
[35]	Rao, L. F.; Srinivasan, T. G.; Garnov, A. Y.; Zanonato, P. L.; Bernardo, P. D. Geochim. Cosmochim. Acta 2004, 68, 4821. doi: 10.1016/j.gca.2004.06.007
[36]	Bennett, D. A.; Hoffman, D.; Nitsche, H.; Russo, R. E.; Torres, R. A.; Baisden, P. A.; Andrews, J. E.; Palmer, C. E. A.; Silva, R. J. Radiochim. Acta 1992, 56, 15. doi: 10.1524/ract.1992.56.1.15
[37]	Oliver, J. H. Radiochim. Acta 1983, 33, 29. doi: 10.1524/ract.1983.33.1.29
[38]	Xia, Y.; Friese, J. I.; Moore, D. A.; Rao, L. F. J. Radioanal. Nucl. Chem. 2006, 268, 445. doi: 10.1007/s10967-006-0189-3
[39]	Inoue, Y.; Tochiyama, O. Bull. Chem. Soc. Jpn. 2006, 58, 2228. doi: 10.1246/bcsj.58.2228
[40]	Rao, L. F.; Tian, G. X.; Xia, Y.; Friese, J. I. J. Therm. Anal. Calorim. 2009, 95, 409. doi: 10.1007/s10973-008-9247-0
[41]	Topin, S.; Aupiais, J.; Baglan, N.; Vercouter, T.; Vitorge, P.; Moisy, P. Anal. Chem. 2009, 81, 5354. doi: 10.1021/ac900275d
[42]	Gainar, I.; Sykes, K. W. J. Chem. Soc. 1964, 4452.
[43]	Rao, P. R. V.; Gudi, N. M.; Bagawde, S. V.; Patil, S. K. J. Inorg. Nucl. Chem. 1979, 41, 235. doi: 10.1016/0022-1902(79)80520-5
[44]	Topin, S.; Aupiais, J.; Baglan, N. Radiochim. Acta 2010, 98, 71.
[45]	Maiwald, M. M.; Fellhauer, D.; Skerencak-Frech, A.; Panak, P. J. Appl. Geochem. 2019, 104, 10. doi: 10.1016/j.apgeochem.2019.03.004
[46]	Tian, G. X.; Rao, L. F.; Xia, Y.; Friese, J. I. J. Therm. Anal. Calorim. 2009, 95, 415. doi: 10.1007/s10973-008-9248-z
[47]	Gaona, X.; Tits, J.; Dardenne, K.; Liu, X.; Rothe, J.; Denecke, M. A.; Wieland, E.; Altmaier, M. Radiochim. Acta 2012, 100, 759. doi: 10.1524/ract.2012.1948
[48]	Gaona, X.; Fellhauer, D.; Altmaier, M. Pure Appl. Chem. 2013, 85, 2027. doi: 10.1351/pac-con-12-12-06
[49]	Reilly, S. D.; Neu, M. P. Inorg. Chem. 2006, 45, 1839. pmid: 16472001
[50]	Cho, H. R.; Jung, E. C.; Park, K. K.; Kim, W. H.; Song, K.; Yun, J. I. Radiochim. Acta 2010, 98, 765. doi: 10.1524/ract.2010.1782
[51]	Cho, H. R.; Jung, E. C.; Park, K. K.; Song, K.; Yun, J. I. Radiochim. Acta 2010, 98, 555. doi: 10.1524/ract.2010.1753
[52]	Rao, L. F.; Tian, G. X.; Bernardo, P. D.; Zanonato, P. L. Chem.-Eur. J. 2011, 17, 10985. doi: 10.1002/chem.v17.39
[53]	Moriyama, H.; Kitamura, A.; Fujiwara, K.; Yamana, H. Radiochim. Acta 1999, 87, 97. doi: 10.1524/ract.1999.87.34.97
[54]	Moriyama, H.; Sasaki, T.; Kobayashi, T.; Takagi, I. J. Alloys Compd. 2006, 408, 1302.
[55]	Kato, Y.; Kimura, T.; Yoshida, Z.; Nitani, N. Radiochim. Acta 1996, 74, 21. doi: 10.1524/ract.1996.74.special-issue.21
[56]	Maya, L. Inorg. Chem. 1984, 16, 3926.
[57]	Pashalidis, I.; Czerwinski, K. R.; Fanghanel, T.; Kim, J. I. Radiochim. Acta 1997, 76, 55. doi: 10.1524/ract.1997.76.12.55
[58]	Matsika, S.; Pitzer, R. M. The Electronic Spectrum of the Neptunyl ion, NpO₂²⁺, Department of Chemistry, The Ohio State University, 1998.
[59]	Ahrland, S.; Brandt, L.; Magnéli, C.; Tolboe, O.; Paasivirta, J. Acta Chem. Scand. 1968, 22, 1579. doi: 10.3891/acta.chem.scand.22-1579
[60]	Gaunt, A. J.; May, I.; Neu, M. P.; Reilly, S. D.; Scott, B. L. Inorg. Chem. 2011, 50, 4244. doi: 10.1021/ic200525u
[61]	Mathur, J. N.; Choppin, G. R. Radiochim. Acta 1994, 64, 175. doi: 10.1524/ract.1994.64.34.175
[62]	Gaunt, A. J.; May, I.; Neu, M. P.; Reilly, S. D.; Scott, B. L. Inorg. Chem. 2011, 50, 4244. doi: 10.1021/ic200525u
[63]	Sawant, R. M.; Chaudhuri, N. K.; Rizvi, G. H.; Patil, S. K. J. Radioanal. Nucl. Chem. 1985, 91, 41. doi: 10.1007/BF02036308

镎和钚与环境中无机阴离子的配位化学研究进展

Advances in Environmental Coordination Chemistry of Np and Pu with Inorganic Anions in Aqueous Solution

RichHTML

PDF

可视化

摘要/Abstract

引用此文

分享此文

图/表 10

参考文献 63

相关文章 15

编辑推荐

相关统计

本文评价

[1]	杨宇洁, 巩宇锈, 顾天航, 张伟贤. 冷冻电子显微镜技术进展及环境研究应用^★[J]. 化学学报, 2023, 81(8): 990-1001.
[2]	王娟, 肖华敏, 谢丁, 郭元茹, 潘清江. 铜掺杂与氮化碳复合氧化锌材料结构和二氧化氮气体传感性质的密度泛函理论计算[J]. 化学学报, 2023, 81(11): 1493-1499.
[3]	韩逸之, 蓝建慧, 刘学, 石伟群. 基于机器学习势函数的熔盐体系分子动力学研究进展[J]. 化学学报, 2023, 81(11): 1663-1672.
[4]	杨学志, 陆达伟, 王伟超, 杨航, 刘倩, 江桂斌. 辨微识源: 纳米颗粒物溯源技术的新进展^※[J]. 化学学报, 2022, 80(5): 652-658.
[5]	刘康, 李斌, 于吉攀, 石伟群. 十四族卡本衍生物: 一类重要的活性中间体[J]. 化学学报, 2022, 80(3): 373-385.
[6]	李程桥, 王一波. 一种量子化学组合方法及其应用于汞对硫酸气溶胶形成影响的研究[J]. 化学学报, 2021, 79(8): 1065-1072.
[7]	蔡政, 张颖雯, 姜立萍, 朱俊杰. 基于类芬顿反应的Mn₃O₄/DOX@Lip纳米递药体系的构建及应用[J]. 化学学报, 2021, 79(4): 481-489.
[8]	闫涛, 刘振华, 宋昕玥, 张书圣. 肿瘤微环境刺激响应型上转换光动力诊疗体系的构建和发展[J]. 化学学报, 2020, 78(7): 657-669.
[9]	李海梅, 罗华健, 肖琦, 杨立云, 黄珊, 刘义. 手性石墨烯量子点与DNA相互作用及其机制研究[J]. 化学学报, 2020, 78(6): 577-586.
[10]	朱桂芬, 陈乐田, 程国浩, 赵娟, 杨灿, 张耀宗, 王醒, 樊静. UiO-66/CoSO₄复合材料对环境中盐酸左氧氟沙星的高效去除[J]. 化学学报, 2019, 77(5): 434-441.
[11]	王宁, 庞宏伟, 于淑君, 顾鹏程, 宋爽, 王宏青, 王祥科. 层状双金属氢氧化物及复合材料对放射性元素铀的吸附及机理研究[J]. 化学学报, 2019, 77(2): 143-152.
[12]	梁珊, 宗敏华, 娄文勇. 酶法催化二氧化碳制备高附加值化学品研究进展[J]. 化学学报, 2019, 77(11): 1099-1114.
[13]	郭肖茹, 阴永光, 谭志强, 刘景富, 江桂斌. 纳米银对水中三价砷的催化氧化研究[J]. 化学学报, 2018, 76(5): 387-392.
[14]	郭宇, 刘瑜, 戚娟娟, 李慧, 赫兰兰, 卢丽男, 刘翠, 宫利东, 赵东霞, 杨忠志. S₄-S₀转化期水结合至放氧复合体可能机制的理论研究[J]. 化学学报, 2017, 75(9): 914-921.
[15]	黄潇月, 王伟, 凌岚, 张伟贤. 纳米零价铁与重金属的反应:“核-壳”结构在重金属去除中的作用[J]. 化学学报, 2017, 75(6): 529-537.