金属有机框架复合材料★

doi:10.6023/A25040117

化学学报 ›› 2025, Vol. 83 ›› Issue (8): 962-980.DOI: 10.6023/A25040117 上一篇

综述

金属有机框架复合材料^★

高春^a, 张松涛^b^,^*(), 庞欢^b^,^c^,^*()

^a 江苏商贸职业学院继续教育学院南通 226011
^b 扬州大学化学化工学院测试中心扬州 225009
^c 南京大学配位化学国家重点实验室南京 210023

投稿日期:2025-04-12 发布日期:2025-06-18
通讯作者: 张松涛, 庞欢

作者简介:

高春, 江苏商贸职业学院继续教育学院副院长, 副教授, 长期从事化学教育研究和高校继续教育工作.

张松涛, 扬州大学测试中心助理研究员. 2016年毕业于南京航空航天大学, 获材料物理与化学博士学位. 近年来主要从事开发应用于电化学储能的MOF基功能材料和介孔基纳米复合材料.

庞欢, 男, 扬州大学化学化工学院院长, 二级教授, 博士生导师. 于2011年获得南京大学理学博士学位. 为教育部青年长江学者、新世纪优秀人才、江苏省杰出青年、英国皇家化学学会会士及全球高被引学者, 兼任《国家科学评论》学科编辑组成员及Nano Res.、Rare Met.等期刊编委. 主要从事纳米配合物及其衍生物的合成、功能应用研究, 尤其是纳米金属有机框架(MOF)的电化学研究.

^★ “中国青年化学家”专辑.

基金资助:
国家自然科学基金项目(52371240); 江苏高校优势学科建设工程和配位化学国家重点实验室资助

Metal-Organic Framework Composites^★

Chun Gao^a, Songtao Zhang^b^,^*(), Huan Pang^b^,^c^,^*()

^a Continuous Education College, Jiangsu Commercial Vocational College, Nantong 226011
^b Testing Center, College of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225009
^c State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210023

Received:2025-04-12 Published:2025-06-18
Contact: Songtao Zhang, Huan Pang
About author:
^★ For the VSI “Rising Stars in Chemistry”.
Supported by:
National Natural Science Foundation of China(52371240); Priority Academic Program Development of Jiangsu Higher Education Institutions and the State Key Laboratory of Coordination Chemistry

文章分享

摘要/Abstract

由于环境问题日益加剧, 能源需求持续增长, 传统材料已难以满足这些领域的进一步需求. 金属有机框架(MOFs)材料因其多孔结构、大比表面积和多功能的特性, 在这些领域中展现出巨大的潜力. 然而, 纯MOFs固有的不稳定性和低导电性限制了其实际应用. 基于MOFs的复合材料在保留单纯MOFs优点的同时, 整合了客体材料(包括无机碳材料、金属氧化物和聚合物等)的功能, 在未来能源和环境等科学领域展现出重要的研究价值. 全面综述了MOF复合材料在电化学储能和吸附领域的应用, 并从维度角度分析了基于MOFs的各种复合材料的物理和化学性质. 在此背景下, 不仅强调了MOF复合材料的优势, 还对其应用效果进行了详细分析和客观概述.

关键词: 金属有机框架, 复合材料, 维度, 电化学储能, 吸附

With the intensification of environmental challenges and the ever-growing global energy demand, conventional materials are increasingly unable to satisfy the stringent requirements in energy and environmental fields. Metal-organic frameworks (MOFs), as a class of crystalline porous materials composed of metal nodes and organic ligands, have emerged as promising candidates due to their tunable pore structures, exceptionally high surface areas, and versatile functionalities. These features enable MOFs to play a significant role in applications such as adsorption and electrochemical energy storage. However, the poor intrinsic electrical conductivity and limited structural stability of pristine MOFs restrict their practical implementation. To address these limitations, MOF-based composites have been developed by integrating MOFs with a variety of guest materials including inorganic carbonaceous materials (e.g., graphene, carbon nanotubes), metal oxides, and conductive polymers. These composites not only retain the inherent advantages of MOFs but also enhance conductivity, mechanical robustness, and chemical stability through synergistic interactions. Importantly, the integration strategies often involve the construction of heterostructures, interface engineering, and the introduction of chemically bonded interfaces, thereby promoting efficient charge transfer and long-term cycling stability. Herein, a comprehensive summary of MOF composites and their emerging applications in electrochemical energy storage systems, such as supercapacitors, lithium-ion batteries, lithium-sulfur batteries and aqueous zinc ion batteries, as well as in environmental adsorption processes targeting heavy metals and CO₂ capture, is offered. The discussion also emphasizes dimensional design from zero-dimensional (0D) nanoparticles to three-dimensional (3D) frameworks, each exhibiting unique advantages in terms of electron transport, ion diffusion, and active site accessibility. The relationships of these composites are analyzed, highlighting how different combinations and morphologies (e.g., core-shell architectures, layered hybrids, and flexible films) influence their functional performance. MOF composites represent a promising frontier for the development of next-generation functional materials. Their tunable dimensionality, enhanced chemical properties and multifunctional adaptability open up new avenues for solving urgent global issues in energy sustainability and environmental remediation.

Key words: metal-organic framework, composite material, dimension, electrochemical energy storage, adsorption

引用此文

高春, 张松涛, 庞欢. 金属有机框架复合材料^★[J]. 化学学报, 2025, 83(8): 962-980.

Chun Gao, Songtao Zhang, Huan Pang. Metal-Organic Framework Composites^★[J]. Acta Chimica Sinica, 2025, 83(8): 962-980.

导出引用 EndNote|Reference Manager|ProCite|BibTeX|RefWorks

分享此文

图/表 21

MOF复合物类型	结构调控的核心策略	电化学性能提升机制	合成工艺
金属氧化物@MOFs	通过金属价态调控与异质界面设计优化电子结构	法拉第赝电容与协同电子传导	溶剂热、电化学沉积
无机碳材料@MOFs	以MOF为前驱体, 通过热解与孔结构设计实现碳基功能化	双电层电容与表面赝电容	高温热解、模板法中空化
聚合物@MOFs	引入多种官能团, 实现氧化还原活性、离子传导和界面稳定化的协同	增强柔性、离子通透性与稳定性	原位聚合、一锅法

表1. 不同类型复合策略在结构调控、电化学性能和合成工艺可扩展性等方面的比较

Table 1. Comparison of different types of composite strategies in structural regulation, electrochemical performance, and scalability of synthesis processes

图1. NiCo-MOF@NiCoO2@Ni的合成示意图[21]

Figure 1. Schematic diagram depicting the synthesis of NiCo-MOF@NiCoO2@Ni[21]

图2. (a, b) NH2-MIL-88B(Fe)和(c, d) g-C3N4/NH2-MIL-88B(Fe)的FESEM[22]及(e) g-C3N4/NH2-MIL-88B(Fe)复合材料在可见光照射下对OFL光降解过程的示意图[22]

Figure 2. FESEM images of (a, b) NH2-MIL-88B(Fe) and (c, d) g-C3N4/NH2-MIL-88B(Fe)[22], and (e) schematic diagram showing OFL photodegradation on the g-C3N4/NH2-MIL-88B(Fe) composite under visible light irradiation[22]

图3. agfZIF-62的制备示意图[24]

Figure 3. Schematic diagram of the synthesis of agfZIF-62[24]

图4. 通过尖端至中心各向异性MOF-on-MOF生长策略, 在晶格失配条件下制备核壳型杂化MOFs (Fe-MIL-88B@Fe-MIL-88C和Fe-MIL-88B@Ga-MIL-88B@Fe-MIL-88C)的示意图[30]

Figure 4. Schematic representation for the production of core-shell-type hybrid MOFs (Fe-MIL-88B@Fe-MIL-88C and Fe-MIL-88B@Ga- MIL-88B@Fe-MIL-88C) via the tip-to-middle anisotropic MOF-On-MOF Growth with Mismatched Cell Lattices[30]

图5. NiFe-UMNs的(a) SEM和(b) AFM[33]以及(c) PtCu@Cu-TCPP UNSs的SEM[34]

Figure 5. (a) SEM and (b) AFM images of NiFe-UMNs[33], and (c) SEM images of PtCu@Cu-TCPP UNSs[34]

图6. (a~d)原位ZIF-8纳米粒子在内介孔通道中的SEM[35]

Figure 6. (a~d) SEM images of in-situ ZIF-8 nanoparticles in mesoporous channels[35]

图7. 不同材料的本征导电率[37]

Figure 7. Intrinsic conductivity of different materials

图8. (a)碳布上NiCo2O4@Ni-MOF核/壳杂化阵列的合成方法示意图[47]、(b) NiCo2O4@Ni-MOF在不同放电电流密度下的比容量[47]、(c) Mn-MOF的线框视图[48]及(d) K0.5Mn2O4@Mn-MOF-8在恒定电流密度2 A•g－1下的循环性能[48]

Figure 8. (a) Schematic illustration of the synthetic approach for the NiCo2O4@Ni-MOF core/shell hybrid arrays on carbon cloth[47], (b) specific capacity of NiCo2O4@Ni-MOF at various discharge current densities[47], (c) wireframe view of the Mn-MOF[48], and (d) cycling performance of K0.5Mn2O4@Mn-MOF-8 at constant current density of 2 A•g－1[48]

图9. 传统多孔超级电容器与多孔聚电解质接枝超级电容器的对比示意图[49]

Figure 9. Comparison diagram of traditional porous supercapacitors and porous polyelectrolyte grafted supercapacitors[49]

MOF复合物	客体材料	应用	比容量	容量保持率	文献
PPHK	聚吡咯	锂离子电池阳极	147.2 mAh•g^－1 at 1 C	86.7% after 800 cycles	[59]
Si/CNTs@ZIF-800N	硅, 碳纳米管	锂离子电池阳极	1223 mAh•g^－1 at 0.1 A•g^－1	98.4% after 100 cycles	[60]
Porous ZnCo₂O₄/C	碳纤维	锂离子电池阳极	1707 mAh•g^－1 at 0.1 A•g^－1	67.1% after 100 cycles	[61]
Co-TCPP MOF/rGO	还原氧化石墨烯	锂离子电池阳极	2317 mAh•g^－1 at 0.1 A•g^－1	≈45.3% after 100 cycles	[62]
PPy@Cu-MOFs	聚吡咯	锂离子电池隔膜	150.2 mAh•g^－1 at 0.5 C	≈100% after 200 cycles	[32]
PP@MIL-101-COOH	聚偏二氟乙烯	锂离子电池隔膜	—	95.9% after 150 cycles	[55]
PH-SSE	聚偏二氟乙烯	锂离子电池电解质	—	85.1% after 300 cycles	[54]
BMOF@HF/H-ZIF-8	聚丙烯腈中空纤维	锂离子电池电解质	—	90.45% after 200 cycles	[58]

表2. MOF复合物在锂离子电池中的应用

Table 2. Application of MOF composites in lithium-ion batteries

图10. (a) Co-PBA/MXene在循环过程中Li＋插入和提取时核壳状结构发生变化的示意图[61]、(b, c) Co-PBA/MXene的储能机制图[61]

Figure 10. (a) Schematic illustration of the core-shell structural changes in Co-PBA/MXene during the insertion and extraction of Li＋ in the cycling process[61], (b, c) diagram of the lithium storage mechanism of Co-PBA/MXene[61]

图11. (a)在裸铜表面Li＋镀/剥离行为的示意图[62]及(b)在PPHK@Cu表面Li＋镀/剥离行为的示意图[62]

Figure 11. (a) schematic diagrams showing the Li＋ plating/stripping behaviors on bare-Cu[62], and (b) schematic diagrams showing the Li＋ plating/stripping behaviors on PPHK@Cu[62]

MOF复合物	客体材料	应用	比容量	容量保持率	文献
Cu-BTC/CNTs	碳纳米管	锂硫电池阴极	805.28 mAh•g⁻¹ at 1 C	60.34% after 200 cycles	[72]
ZIF@T-PVDF	聚偏二氟乙烯	锂硫电池隔膜	1324.2 mAh•g⁻¹ at 2 C	—	[73]
CSUST-1/CNT	CNT	锂硫电池隔膜	1468 mAh•g⁻¹ at 0.1 C	—	[74]
UiO-66/ACNT	酸处理碳纳米管	锂硫电池隔膜	4.01 mAh•cm^－2 at 0.2C	—	[75]

表3. MOF复合物应用于锂硫电池

Table 3. Application of MOF composites in lithium sulfur batteries

图12. MOF复合物作为锂硫电池隔膜材料来限制多硫化物的穿梭效应的示意图[74]

Figure 12. Schematic diagram of MOF composite as the Li-S battery separator to limit the shuttle effect of polysulfides[74]

MOF复合物	客体材料	应用	比容量	容量保持率	文献.
MIL-88B(V)@rGO	氧化石墨烯	锌离子电池阴极	480 mAh•g^－1 at 0.05 A•g^－1	80.3% after 400 cycles	[84]
Mn-MOF/CNT	碳纳米管	锌离子电池阴极	260 mAh•g^－1 at 0.05 A•g^－1	≈100% after 900 cycles	[85]
V-MOF@graphene	石墨烯	锌离子电池阴极	342 mAh•g^－1 at 0.1A•g^－1	≈89% after 100 cycles	[86]
MXene/Cu-THBQ	MXene	锌离子电池阳极	235.4 mAh•g^－1 at 0.2 A•g^－1	98.7% after 400 cycles	[87]

表4. MOF复合物在水系锌离子电池中的应用

Table 4. Application of MOF composites in aqueous zinc ion battery

图13. (a1~c1) V-PBA正极在3 mol/L Zn(OTf)2、盐水和共晶电解质中的溶解行为示意图[89], (a2~c2)锌枝晶在3 mol/L Zn(OTf)2、盐水和共晶电解质中的生成过程示意图[89]及(d) V-PBA储存Zn2＋机制的示意图[89]

Figure 13. (a1~c1) Schematic diagram of the dissolution behavior of the V-PBA cathode in 3 mol/L Zn(OTf)2, saline, and eutectic electrolytes[89], (a2~c2) schematic diagram of the formation process of zinc dendrites in 3 mol/L Zn(OTf)2, saline, and eutectic electrolytes[[89], and (d) schematic diagram of the mechanism of Zn2＋ storage in V-PBA[89]

图14. (a~c) Zn-P负极的非原位SEM图像[87]及(d~f) M3DP-MXene/Cu-THBQ/Zn-P负极的非原位SEM图像[87]

Figure 14. (a~c) Ex situ SEM images of the Zn-P anode[87], and (d~f) Ex situ SEM images of the M3DP-MXene/Cu-THBQ/Zn-P anode[87]

图15. (a) AOPAN/ZIF的合成示意图[96]、(b)接触时间对UN-PA-AO-PANF-2吸收U(VI)的影响[97]和(c) ZIF-67/SAP复合水凝胶的合成示意图[98]

Figure 15. (a) Schematic synthetic route of AOPAN/ZIF[96], (b) effect of contact time on the uptake of U(VI) by UN-PA-AO-PANF-2[97], and (c) pathway to fabricate the ZIF-67/SAP composite hydrogel[98]

图16. (a) BDB-MIL-125(Ti)@Fe3O4与Pb(Ⅱ)之间的吸附机制[99]和(b) BDB-MIL-125(Ti)@Fe3O4与Pb(Ⅱ)吸附时的结合能[99]

Figure 16. (a) Adsorption binding mechanisms between BDB-MIL-125(Ti)@Fe3O4 and Pb(II)[99], and (b) binding energy of BDB-MIL-125(Ti)@Fe3O4 and Pb(Ⅱ)[99]

图17. (a) PI-UiO/GOs的交联、缩合和亲核反应机理以及吸附相互作用位点[101]及(b)通过将CB6结合到铬基MIL-101中来创建功能性杂化材料的概念图[104]

Figure 17. (a) Cross-linking, condensation, and nucleophilic reaction mechanism of PI-UiO/GOs and adsorption interaction sites[101] and (b) conceptual diagram of functional hybrid materials by incorporating CB6 into chromium based MIL-101[104]

参考文献 103

[1]	Wen, Z.; Mu, X.; Sun, X.; Xu, Z.; Zheng, M.; Zhou, H.; He, P. Angew. Chem., Int. Ed. 2025, 64, e202424121.
	Zhu, W.; Hu, W.; Wei, Y.; Zhang, Y.; Pan, K.; Zhang, S.; Hang, X.; Zheng, M.; Pang, H. Adv. Funct. Mater. 2024, 34, 2409390.
[2]	Ni, H.; Wang, Y.; Yao, K.; Wang, L.; Huang, J.; Xiao, Y.; Chen, H.; Liu, B.; Yang, C. Y.; Zhao, J. Nat. Commun. 2024, 15, 1.
[3]	Ilić, N.; Tan, K.; Mayr, F.; Hou, S.; Aumeier, B. M.; Morales, E. M. C.; Hübner, U.; Cookman, J.; Schneemann, A.; Gagliardi, A.; Drewes, J. E.; Fischer, R. A.; Mukherjee, S. Adv. Mater. 2025, 37, 2413120.
[4]	Chen, Y.; Zhang, S.; Chen, Y.; Ding, H.; Yao, S.; Tang, Y.; Qiu, Z.; Xu, K.; Hu, Y.; Gong, H.; Hu, Y.; Pang, H. Nano Res. 2025, 18, 94907446.
[5]	Zhou, H.; Gu, S.; Lu, Y.; Zhang, G.; Li, B.; Dou, F.; Cao, S.; Li, Q.; Sun, Y.; Shakouri, M.; Pang, H. Adv. Mater. 2024, 36, 2401856.
[6]	Yao, S.; Zhang, S.; Zhang, G.; Tang, Y.; Zhu, R.; Peng, Y.; Chen, Y.; Pang, H. Inorg. Chem. 2023, 62, 16038.
[7]	He, Y.; Tan, Y.; Zhang, J. Acta Chim. Sinica 2014, 72, 1228 (in Chinese).
	(何燕萍, 谭衍曦, 张健, 化学学报, 2014, 72, 1228.) doi: 10.6023/A14090632
[8]	Noman, M.; Saqib, Q. M.; Ameen, S.; Patil, S. R.; Patil, C. S.; Kim, J.; Ko, Y.; Kim, B.; Bae, J. Adv. Sci. 2024, 11, 2404993.
[9]	Li, Y.; Zou, B.; Xiao, A.; Zhang, H. Chin. J. Chem. 2017, 35, 1501.
[10]	Xie, Q.; Ou, H.; Yang, Q.; Lin, X.; Zeb, A.; Li, K.; Chen, X.; Ma, G. Dalton Trans. 2021, 50, 9669.
[11]	Jiao, L.; Seow, J. Y. R.; Skinner, W. S.; Wang, Z. U.; Jiang, H.-L. Mater. Today 2019, 27, 43.
[12]	Guo, C.; Ma, X.; Wang, B. Acta Chim. Sinica 2021, 79, 967 (in Chinese).
	(郭彩霞, 马小杰, 王博, 化学学报, 2021, 79, 967.) doi: 10.6023/A21040173
[13]	Zhang, J.; Li, P.; Zhang, X.; Ma, X.; Wang, B. Acta Chim. Sinica 2020, 78, 597 (in Chinese).
	(张晋维, 李平, 张馨凝, 马小杰, 王博, 化学学报, 2020, 78, 597.) doi: 10.6023/A20050153
[14]	Dai, M.; Wang, J.; Li, L.; Wang, Q.; Liu, M.; Zhang, Y. Acta Chim. Sinica 2020, 78, 355 (in Chinese).
	(代迷迷, 王健, 李麟阁, 王琪, 刘美男, 张跃钢, 化学学报, 2020, 78, 355.) doi: 10.6023/A20010017
[15]	Carbonell, C.; Linares-Moreau, M.; Borisov, S. M.; Falcaro, P. Adv. Mater. 2024, 36, 2408770.
[16]	Oh, H.; Lee, G.; Oh, M. Small 2024, 20, 2306543.
[17]	Zhou, X.; Wang, T.; He, D.; Chen, P.; Liu, H.; Lv, H.; Wu, H.; Su, D.; Pang, H.; Wang, C. Angew. Chem., Int. Ed. 2024, 63, e202408989.
[18]	Yang, G.; Wang, D.; Wang, Y.; Hu, W.; Hu, S.; Jiang, J.; Huang, J.; Jiang, H.-L. J. Am. Chem. Soc. 2024, 146, 10798. doi: 10.1021/jacs.4c00972 pmid: 38579304
[19]	Zhang, C.; Xie, C.; Gao, Y.; Tao, X.; Ding, C.; Fan, F.; Jiang, H. Angew. Chem., Int. Ed. 2022, 61, e202204108.
[20]	Mohanty, A.; Kang, K.; Saravanakumar, B.; Ramadoss, A.; Jang, J. Small 2024, 20, 2308771.
[21]	Su, Q.; Li, J.; Yuan, H.; Wang, B.; Wang, Y.; Li, Y.; Xing, Y. Chem. Eng. J. 2022, 427, 131594.
[22]	Shokouhfar, N.; Kilaparthi, S. K.; Barras, A.; Abraham, B. M.; Addad, A.; Roussel, P.; Bhatt, S.; Jain, S. L.; Szunerits, S.; Morsali, A.; Boukherroub, R. Inorg. Chem. 2024, 63, 2327.
[23]	Yang, Z.; Belmabkhout, Y.; McHugh, L. N.; Ao, D.; Sun, Y.; Li, S.; Qiao, Z.; Bennett, T. D.; Guiver, M. D.; Zhong, C. Nat. Mater. 2023, 22, 888.
[24]	Huang, G.; Chen, Y.; Jiang, H. Acta Chim. Sinica 2016, 74, 113 (in Chinese). doi: 10.6023/A15080547
	(黄刚, 陈玉贞, 江海龙, 化学学报, 2016, 74, 113.) doi: 10.6023/A15080547
[25]	Sun, D.; Mo, F.; Zhou, Y.; Lu, J.; Duan, H. Mater. Des. 2024, 239, 112804.
[26]	Kaur, R.; Rana, A.; Singh, R. K.; Chhabra, V. A.; Kim, K.-H.; Deep, A. RSC Adv. 2017, 7, 29015.
[27]	Chen, Y.; Liang, J.; Su, Y.; Zhu, G.; Xu, H.; Ding, H.; Zhang, G.; Yu, D.; Shen, Z.; Zhang, Y.; Huang, W.; Pang, H. Sci. China: Chem. 2025, 68, 2378.
[28]	Yang, D.; Liang, Z.; Tang, P.; Zhang, C.; Tang, M.; Li, Q.; Biendicho, J. J.; Li, J.; Heggen, M.; Dunin‐Borkowski, R. E.; Xu, M.; Llorca, J.; Arbiol, J.; Morante, J. R.; Chou, S.; Cabot, A. Adv. Mater. 2022, 34, 2108835.
[29]	Lee, G.; Lee, S.; Oh, S.; Kim, D.; Oh, M. J. Am. Chem. Soc. 2020, 142, 3042.
[30]	Lü, L.; Zhao, Y.; Wei, Y.; Wang, H. Acta Chim. Sinica 2021, 79, 869 (in Chinese).
	(吕露茜, 赵娅俐, 魏嫣莹, 王海辉, 化学学报, 2021, 79, 869.) doi: 10.6023/A21030099
[31]	Liu, Z.; Hu, R.; Yu, R.; Zheng, M.; Zhang, Y.; Chen, X.; Shen, L.; Xia, Y. Nano Lett. 2024, 24, 4908.
[32]	Hai, G.; Jia, X.; Zhang, K.; Liu, X.; Wu, Z.; Wang, G. Nano Energy 2018, 44, 345.
[33]	Pi, Y.; Qiu, Z.; Fan, Y.; Mao, Q.; Zhang, G.; Wang, X.; Chang, H.-H.; Chen, H.-J.; Chen, T.-Y.; Chen, H.-Y.; Zhang, S.; Shakouri, M.; Pang, H. Nano Lett. 2024, 24, 13760.
[34]	Zhang, S.; Li, Y.; Zhuang, X.; Hu, Y.; Xu, K.; Zhang, G.; Pi, Y.; Tang, Y.; Hu, J.; Zang, R.; Qiu, Z.; Zhou, H.; Yu, F.; Shakouri, M.; Pang, H. Adv. Mater. 2025, 37, 2418344.
[35]	Liu, Y.; Xin, N.; Yang, Q.; Shi, W. J. Colloid Interface Sci. 2021, 583, 288.
[36]	Safy, M. E. A.; Haikal, R. R.; Elshazly, B.; Hamdy, A.; Ali, F.; Maarouf, A. A.; Alkordi, M. H. Appl. Mater. Today 2020, 19, 100604.
[37]	Wang, B.; Liu, S.; Liu, L.; Song, W.-W.; Zhang, Y.; Wang, S.-M.; Han, Z.-B. J. Mater. Chem. A 2021, 9, 2948.
[38]	Zhou, H.; Zhu, G.; Dong, S.; Liu, P.; Lu, Y.; Zhou, Z.; Cao, S.; Zhang, Y.; Pang, H. Adv. Mater. 2023, 35, 2211523.
[39]	Zhang, S.; Zheng, M.; Tang, Y.; Zang, R.; Zhang, X.; Huang, X.; Chen, Y.; Yamauchi, Y.; Kaskel, S.; Pang, H. Adv. Funct. Mater. 2022, 32, 2204714.
[40]	Wu, H.; Zhang, W.; Kandambeth, S.; Shekhah, O.; Eddaoudi, M.; Alshareef, H. N. Adv. Energy Mater. 2019, 9, 1900482.
[41]	Liu, L.; Yan, Y.; Cai, Z.; Lin, S.; Hu, X. Adv. Mater. Interfaces 2018, 5, 1701548.
[42]	Ibrahim, I.; Zheng, S.; Foo, C. Y.; Huang, N. M.; Lim, H. N. J. Energy Storage 2021, 43, 103304.
[43]	Saxena, N.; Bondarde, M. P.; Lokhande, K. D.; Bhakare, M. A.; Dhumal, P. S.; Some, S. Chem. Phys. Lett. 2024, 856, 141605.
[44]	Kumaraguru, S.; Yesuraj, J.; Mohan, S. Composites, Part B 2020, 185, 107767.
[45]	Zheng, S.; Li, Q.; Xue, H.; Pang, H.; Xu, Q. Nati. Sci. Rev. 2020, 7, 305.
[46]	Li, G.; Cai, H.; Li, X.; Zhang, J.; Zhang, D.; Yang, Y.; Xiong, J. ACS Appl. Mater. Interfaces 2019, 11, 37675.
[47]	Yao, S.; Jiao, Y.; Sun, S.; Wang, L.; Li, P.; Chen, G. ACS Sustainable Chem. Eng. 2020, 8, 3191.
[48]	Qing, L.; Jiang, J. ACS Nano 2023, 17, 17122.
[49]	Shao, L.; Wang, Q.; Ma, Z.; Ji, Z.; Wang, X.; Song, D.; Liu, Y.; Wang, N. J. Power Sources 2018, 379, 350.
[50]	Yue, T.; Douka, A. I.; Qi, K.; Qiu, Y.; Guo, X.; Xia, B. Y. J. Mater. Chem. A 2021, 9, 21799.
[51]	Singh, J.; Choudhury, A.; Ahmad, M. W.; Syed, A.; AL-Shwaiman, H. A.; Subramaniam, M.; Yang, D.-J. J. Alloys Compd. 2025, 1014, 178638.
[52]	Liu, F.; Zuo, P.; Li, J.; Shi, P.; Shao, Y.; Chen, L.; Tan, Y.; Ma, T. J. Energy Chem. 2024, 93, 282.
[53]	Chai, Y.; Ning, D.; Zhou, D.; Gao, J.; Ni, J.; Zhang, G.; Gao, R.; Wu, W.; Wang, J.; Li, Y. Nano Energy 2024, 130, 110160.
[54]	Hu, Q.; Han, G.; Wang, A.; Gao, K.; Liao, J.; Ding, M.; Zhou, Y.; Dominko, R.; Wang, H.; Yao, J. Chem. Eng. J. 2024, 497, 154608.
[55]	Yu, Y.; Zhang, X. Acta Chim. Sinica 2020, 78, 1434 (in Chinese).
	(于越, 张新波, 化学学报, 2020, 78, 1434.) doi: 10.6023/A20070290
[56]	Chang, Z.; Qiao, Y.; Yang, H.; Deng, H.; Zhu, X.; He, P.; Zhou, H. Acta Chim. Sinica 2021, 79, 139 (in Chinese). doi: 10.6023/A20090442
	(常智, 乔羽, 杨慧军, 邓瀚, 朱星宇, 何平, 周豪慎, 化学学报, 2021, 79, 139.) doi: 10.6023/A20090442
[57]	Li, S.; Chen, Y.; Leng, X.; Yang, M.; Arifeen, W. U.; Ko, T. J. Chem. Eng. J. 2024, 500, 157209.
[58]	Cyril Karima, N.; Jin, S.; Mook Choi, S.; Jenerali Nyamtara, K.; Maldonado Nogales, P.; Cuong Nguyen, M.; Hoon Kim, S.; Nam Lim, S.; Jeong, S.-K.; Kim, H.-K.; Ho Seo, M.; Ahn, W. Chem. Eng. J. 2024, 497, 154634.
[59]	Gu, Z.; Miao, Y.; Li, W.; Chen, Y.; Xia, X.; Chen, G.; Liu, H. ACS Appl. Energy Mater. 2020, 3, 3815.
[60]	Dai, Z.; Long, Z.; Li, R.; Shi, C.; Qiao, H.; Wang, K.; Liu, K. ACS Appl. Energy Mater. 2020, 3, 12378.
[61]	Han, Y.; Liu, Z.; Zheng, F.; Bai, Y.; Zhang, Z.; Li, X.; Xiong, W.; Zhang, J.; Yuan, A. J. Alloys Compd. 2021, 881, 160531.
[62]	Zhu, H.; Yu, Z.; Song, Y.; Liu, S.; Zhao, L.; Guo, J.; Li, W.; Han, X.; Wen, Z. ChemPhysChem 2025, 26, e202401007.
[63]	Qiao, Y.; Hu, Y.; Qian, Z.; Qu, M.; Liu, Z. J. Colloid Interface Sci. 2025, 684, 678.
[64]	Shi, Y.; Song, G.; Yang, B.; Tang, Y.; Liu, Z.; Zhang, Z.; Shakouri, M.; Cheng, J.; Pang, H. Adv. Mater. 2025, 37, 2416665.
[65]	Ma, Y.; Wei, L.; He, Y.; Yuan, X.; Su, Y.; Gu, Y.; Li, X.; Zhao, X.; Qin, Y.; Mu, Q.; Peng, Y.; Sun, Y.; Deng, Z. Angew. Chem., Int. Ed. 2022, 61, e202116291.
[66]	Li, M.; Cheng, S.; Zhang, J.; Huang, C.; Gu, J.; Han, J.; Xu, X.; Chen, X.; Zhang, P.; You, Y. Chem. Eng. J. 2024, 487, 150709.
[67]	Jiang, Q.; Xiong, P.; Liu, J.; Xie, Z.; Wang, Q.; Yang, X.; Hu, E.; Cao, Y.; Sun, J.; Xu, Y.; Chen, L. Angew. Chem., Int. Ed. 2020, 59, 5273.
[68]	Zhang, C.; Shen, L.; Shen, J.; Liu, F.; Chen, G.; Tao, R.; Ma, S.; Peng, Y.; Lu, Y. Adv. Mater. 2019, 31, 1808338.
[69]	Li, Z.; Wang, J.; Yuan, H.; Yu, Y.; Tan, Y. Adv. Funct. Mater. 2024, 34, 2405890.
[70]	Zhou, L.; Pan, H.; Yin, G.; Xiang, Y.; Tan, P.; Li, X.; Jiang, Y.; Xu, M.; Zhang, X. Adv. Funct. Mater. 2024, 34, 2314246.
[71]	Deng, T.; Men, X.-L.; Jiao, X.-C.; Wang, J. Ceram. Int. 2022, 48, 4352.
[72]	Feng, Y.; Wang, G.; Kang, W.; Deng, N.; Cheng, B. Electrochim. Acta 2021, 365, 137344.
[73]	Jin, H.-G.; Wang, M.; Wen, J.-X.; Han, S.-H.; Hong, X.-J.; Cai, Y.-P.; Li, G.; Fan, J.; Chao, Z.-S. ACS Appl. Mater. Interfaces 2021, 13, 3899.
[74]	Li, X.; Yan, Z.; Zhang, J.; Huang, Z.; Li, F.; Yang, L.; Huang, J.; Wang, G.; Xu, G. Chem. Eng. J. 2024, 493, 152554.
[75]	Sun, Z.; Sun, B.; Xue, J.; He, J.; Zhao, R.; Chen, Z.; Sun, Z.; Liu, H. K.; Dou, S. X. Adv. Funct. Mater. 2025, 35, 2414671.
[76]	Zhang, H.; Zhao, W.; Zou, M.; Wang, Y.; Chen, Y.; Xu, L.; Wu, H.; Cao, A. Adv. Energy Mater. 2018, 8, 1800013.
[77]	Qi, J.; Zhang, M.; Xu, T.; Liu, K.; Wang, Y.; Zhang, H.; Wang, X.; Yuan, Z.; Si, C. Chem. Eng. J. 2024, 500, 157318.
[78]	Hong, X.-J.; Song, C.-L.; Yang, Y.; Tan, H.-C.; Li, G.-H.; Cai, Y.-P.; Wang, H. ACS Nano 2019, 13, 1923.
[79]	Bai, S.; Liu, X.; Zhu, K.; Wu, S.; Zhou, H. Nat. Energy 2016, 1, 16094.
[80]	Liu, B.; Taheri, M.; Torres, J. F.; Fusco, Z.; Lu, T.; Liu, Y.; Tsuzuki, T.; Yu, G.; Tricoli, A. ACS Nano 2020, 14, 13852.
[81]	Wu, X.; Luo, L.; Peng, S.; Zhang, M.; Li, X.; Meng, X.; Yin, C.; Wu, X.; Wu, X. Chem. Eng. J. 2024, 482, 148836.
[82]	Xu, X.; Li, S.; Cao, Z.; Yang, S.; Li, B. Adv. Energy Mater. 2024, 14, 2303971.
[83]	Jia, D.; Shen, Z.; Lv, Y.; Chen, Z.; Li, H.; Yu, Y.; Qiu, J.; He, X. Adv. Funct. Mater. 2024, 34, 2308319.
[84]	Zhang, J. J. Energy Storage 2024, 76, 109873.
[85]	Gong, L.; Zhang, Y.; Li, Z. Mater. Today Chem. 2022, 23, 100731.
[86]	Lu, H.; Hu, J.; Zhang, K.; Zhao, J.; Deng, S.; Li, Y.; Xu, B.; Pang, H. Adv. Mater. 2024, 36, 2309753.
[87]	Zhong, J.; Xu, Q.; Li, R.; Yuan, D. Appl. Catal., B 2025, 361, 124615.
[88]	Shi, Y.; Yang, B.; Song, G.; Chen, Z.; Shakouri, M.; Zhou, W.; Zhang, X.; Yuan, G.; Pang, H. Angew. Chem., Int. Ed. 2024, 63, e202411579.
[89]	Gopalakrishnan, M.; Kao-ian, W.; Aupama, V.; Etesami, M.; Ganesan, S.; Theerthagiri, J.; Choi, M. Y.; Mohamad, A. A.; Kheawhom, S. Chem. Eng. J. 2024, 484, 149624.
[90]	Kim, E.; Choi, I.; Nam, K. W. Electrochim. Acta 2022, 425, 140648.
[91]	Yuan, G.; Su, Y.; Zhang, X.; Gao, B.; Hu, J.; Sun, Y.; Li, W.; Zhang, Z.; Shakouri, M.; Pang, H. Nati. Sci. Rev. 2024, 11, nwae336.
[92]	Lü, T.; Ma, W.; Zhan, D.; Zou, Y.; Li, J.; Feng, M.; Huang, X. Acta Chim. Sinica 2022, 80, 640 (in Chinese).
	(吕天天, 马文, 詹冬笋, 邹燕敏, 李继龙, 冯美玲, 黄小荥, 化学学报, 2022, 80, 640.) doi: 10.6023/A21120614
[93]	Ahmadijokani, F.; Tajahmadi, S.; Bahi, A.; Molavi, H.; Rezakazemi, M.; Ko, F.; Aminabhavi, T. M.; Arjmand, M. Chemosphere 2021, 264, 128466.
[94]	Ji, C.; Ren, Y.; Yu, H.; Hua, M.; Lv, L.; Zhang, W. Chem. Eng. J. 2022, 430, 132960.
[95]	Li, W.; Liu, Y.-Y.; Bai, Y.; Wang, J.; Pang, H. J. Hazardous Mater. 2020, 395, 122692.
[96]	Zhang, G.; Fan, H.; Zhou, R.; Yin, W.; Wang, R.; Yang, M.; Xue, Z.; Yang, Y.; Yu, J. J. Hazardous Mater. 2022, 424, 127273.
[97]	Bai, Z.; Liu, Q.; Zhang, H.; Yu, J.; Chen, R.; Liu, J.; Song, D.; Li, R.; Wang, J. ACS Appl. Mater. Interfaces 2020, 12, 18012.
[98]	Huang, Z.; Xiong, C.; Ying, L.; Wang, W.; Wang, S.; Ding, J.; Lu, J. J. Hazard. Mater. 2022, 432, 128700.
[99]	Yang, W.; Liang, H.; Qiao, Z. Acta Chim. Sinica 2018, 76, 785 (in Chinese).
	(杨文远, 梁红, 乔智威, 化学学报, 2018, 76, 785.) doi: 10.6023/A18070293
[100]	Ning, H.; Yang, Z.; Yin, Z.; Wang, D.; Meng, Z.; Wang, C.; Zhang, Y.; Chen, Z. ACS Appl. Mater. Interfaces 2021, 13, 17781.
[101]	Muschi, M.; Devautour-Vinot, S.; Aureau, D.; Heymans, N.; Sene, S.; Emmerich, R.; Ploumistos, A.; Geneste, A.; Steunou, N.; Patriarche, G.; De Weireld, G.; Serre, C. J. Mater. Chem. A 2021, 9, 13135.
[102]	Lin, J.-B.; Nguyen, T. T. T.; Vaidhyanathan, R.; Burner, J.; Taylor, J. M.; Durekova, H.; Akhtar, F.; Mah, R. K.; Ghaffari-Nik, O.; Marx, S.; Fylstra, N.; Iremonger, S. S.; Dawson, K. W.; Sarkar, P.; Hovington, P.; Rajendran, A.; Woo, T. K.; Shimizu, G. K. H. Science 2021, 374, 1464.
[103]	Liang, J.; Nuhnen, A.; Millan, S.; Breitzke, H.; Gvilava, V.; Buntkowsky, G.; Janiak, C. Angew. Chem., Int. Ed. 2020, 59, 6068.

金属有机框架复合材料^★

Metal-Organic Framework Composites^★

RichHTML

PDF

可视化

摘要/Abstract

引用此文

分享此文

图/表 21

参考文献 103

相关文章 15

编辑推荐

相关统计

本文评价

[1]	吴子林, 张璐, 陈杨, 李晋平, 李立博. 乙烷选择性金属有机框架材料的结构设计与分离应用^★[J]. 化学学报, 2025, 83(8): 917-936.
[2]	朱永朝, 刘冰洁, 梁文杰, 徐海. 多功能MOFs隔离膜用于锂硫电池的研究[J]. 化学学报, 2025, 83(8): 861-867.
[3]	杨天宇, 代佳楠, 张玉洁, 薛娟琴, 马晶. 层间阴离子可调控LiAl-LDHs的制备及锂吸附性能研究[J]. 化学学报, 2025, 83(6): 569-578.
[4]	赵梦飞, 韩赫兴, 杨幼明, 李庭刚. 离子吸附型稀土矿生物浸出技术研究进展[J]. 化学学报, 2025, 83(4): 415-427.
[5]	王跃, 邹莹, 张元, 郑舒婕, 王恒宇, 刘天赋, 李仁富. 锆基金属有机框架材料在氧传感器上的应用[J]. 化学学报, 2025, 83(1): 45-51.
[6]	康健, 石梓煊, 李景梅. 高抗菌性光催化材料的制备及LED光驱动其抗菌性能研究[J]. 化学学报, 2024, 82(9): 962-970.
[7]	王馨雨, 许雄文. SnCl₂敏化的TiO₂表面对PbI₂粒子的诱导吸附[J]. 化学学报, 2024, 82(8): 865-870.
[8]	王南南, 陈玉贞. CoNi-MOF-74/泡沫镍衍生的CoNi@C/NF复合物用于高效有机电合成[J]. 化学学报, 2024, 82(6): 621-628.
[9]	周何鑫, 崔青云, 胡雪敏, 杨文秀, 田肖, 王硕. 金属有机框架衍生氮掺杂碳限域钴原子簇催化硝基化合物转移加氢[J]. 化学学报, 2024, 82(5): 503-510.
[10]	徐晗, 王聪芝, 刘峙嵘, 石伟群. 海水提铀吸附材料及官能团配位机理研究进展[J]. 化学学报, 2024, 82(4): 458-470.
[11]	刘洋, 高丰琴, 马占营, 张引莉, 李午戊, 侯磊, 张小娟, 王尧宇. 一例钴基金属有机框架化合物活化过氧单硫酸盐高效降解水中亚甲基蓝研究[J]. 化学学报, 2024, 82(2): 152-159.
[12]	林航青, 马若茹, 江怡蓝, 许木榕, 林洋彭, 杜克钊. 用于卤素捕获的材料研究进展[J]. 化学学报, 2024, 82(1): 62-74.
[13]	韩玉淳, 王毅琳. 长效抗菌材料的研究现状与展望^★[J]. 化学学报, 2023, 81(9): 1196-1201.
[14]	王华高, 程群峰. 冰模板技术仿生构筑层状高分子纳米复合材料的研究进展^★[J]. 化学学报, 2023, 81(9): 1231-1239.
[15]	孙博, 琚雯雯, 王涛, 孙晓军, 赵婷, 卢晓梅, 陆峰, 范曲立. 高分散共轭聚合物-金属有机框架纳米立方体的制备及抗肿瘤应用[J]. 化学学报, 2023, 81(7): 757-762.

金属有机框架复合材料★

Metal-Organic Framework Composites★

RichHTML

PDF

可视化

摘要/Abstract

引用此文

分享此文

图/表 21

参考文献 103

相关文章 15

编辑推荐

相关统计

本文评价

金属有机框架复合材料^★

Metal-Organic Framework Composites^★