化学学报 ›› 1981, Vol. 39 ›› Issue (1): 55-62. 上一篇    下一篇

论文

微量氧监测器的研究

冯强生, 刘国梁, 潘淑端, 赵匡宝, 于诗广   

  1. 中国科学院上海冶金研究所
  • 投稿日期:1979-01-20 发布日期:2013-06-03

STUDY ON TRACE OXYGEN MONITOR

FENG QIANG-SHENG, LIU GUO-LIANO, PAN SHU-DUAN, ZHAO KUANG-BAO, YU SHI-GUANG   

  1. Shanghai Institute of Metallurgy, Academia Sinica
  • Received:1979-01-20 Published:2013-06-03

本文对极谱式氧电极进行了以下的研究:1.推导了电极体内溶解氧扩散电流方程式,并作了验证:2.找出了残余电流起因,主要受铂-玻璃界面封接状态的影响;3.推导了所设计的电极热传导方程式,解决了温度同步问题;4.提出防止电极钝化的方法;5.设计了低漂移高阻抗放大器线路.通过以上的研究提出了一种能测出2ppm氧,响应时间小于10分钟,寿命超过5000小时的氧电极.

In this papor a number of problems in connection with the polarographic oxygen electrode are discussed.1.The equation of diffusion current for the dissolved oxygen in the body of the electrode has been derived and examined experimentally.2.The sources of the residual current has been analysed and found to be attributed to the orovice involved in Pt-glass border.3.According to the calculation of heat conduction of the system designed by us,the electrode should be independent of temperature.4.A design of the detector is described,theroby the contamination of the working electrode surface by the surface active substances can bo avoided.