化学学报 ›› 1983, Vol. 41 ›› Issue (10): 966-970. 上一篇    下一篇

研究论文

具有不同长度碳链的不对称四苯基卟啉及其金属配合物的合成

高福;何云陔;王秀华;姚道清;徐惠芳;王敏   

  1. 中国科学院兰州化学物理研究所
  • 发布日期:1983-10-15

The synthesis of asymmetrically substituted porphyrins and their metal complexes

GAO FU;HE YUNGAI;WANG XIUHUA;YAO DAOQING;XU HUIFANG;WANG MIN   

  • Published:1983-10-15

关键词: 卟吩 P, 金属络合物

Three unsymmetrically substituted porphyrins, namely 5-(4-n- amyloxyphenyl) 10, 15, 20-triphenyl porphenyl porphyrin and 5-(4- n-decyloxyphenyl) 10, 15, 20-triphenyl porphyrin, 5-(4-n- hexadecyloxyphenyl) 10, 15, i0-triphenyl porphyrin were synthesised. Reaction of these compounds with copper, zinc, cobalt and nickel salt gave the metal complexes. These compounds were characterized by elemental analyses, IR, visible and NMR spectra.

Key words: PORPHINE P, METAL COMPLEX

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