化学学报 ›› 1989, Vol. 47 ›› Issue (5): 516-517. 上一篇    

研究论文

一种结构新颖的二苯并碘五环内盐的合成

侯自杰;陈渝;李裕林   

  1. 兰州大学有机化学研究所
  • 发布日期:1989-05-15

Synthesis of a new dibenziodolium inner salt

HOU ZIJIE;CHEN YU;LI YULIN   

  • Published:1989-05-15

研究了用Eschweiler-Clarke反应的3,7-二氨基二苯并碘五环 氯化物的N-甲基化,生成了一个新的二苯并碘五环内 盐, 用IR, NMR和MS测定了内 盐的结构.

关键词: 构效关系, 质子磁共振谱法, 五员杂环化合物, 抗辐射性, 碘杂环化合物, 二苯并化合物, 内翁盐

N-Methylation of 3,7-diaminodibenziodolium chloride (I) by Eschweiler-Clarke reaction resulted in the formation of a new dibenziodolium inner salt II rather than the expected alkylation product. The structure of II was established by IR, NMR, and mass spectra.

Key words: STRUCTURE ACTIVITY RELATIONSHIP, PROTON MAGNETIC RESONANCE SPECTROMETRY, FIVE MEMBER RING HETEROCYCLIC COMPOUNDS, RADIORESISTANCE, IODINE HETEROCYCLIC COMPOUNDS, DIBENZO COMPOUNDS, YLIDE

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