化学学报 ›› 1990, Vol. 48 ›› Issue (7): 705-708. 上一篇    下一篇

研究论文

绣毛野桐化学成分的研究I:野桐酮的化学结构

唐宗俭;宋纯清;冯胜初;杨益平;徐任生;钟琼芯;钟义   

  1. 中国科学院上海药物研究所;海南大学生物系
  • 发布日期:1990-07-15

Studies on chemical constituents of mallotus anomalus. I: The structure of anomaluone

TANG ZONGJIAN;SONG CHUNQING;FENG SHENGCHU;YANG YIPING;XU RENSHENG;ZHONG QIONGXIN;ZHONG YI   

  • Published:1990-07-15

从海南岛产大戟科植物特有种绣毛野桐(Mallotus anomalusMeer et Chun)中, 分得两个结晶, 其一为ent-Kaurenc型新二萜野桐酮(anomaluone,1)。另一结晶为已知物橙酰胺乙酸酯(aurantiamideacetate)。

关键词: 化学成分, 乙酸酯, 酰胺, 红外分光光度法, 红外分光光度法, 质谱法, 核磁共振, 二萜, 四环二萜, 抗癌药(中药)

Two compounds were separated from M. anomalus (Euphorbiaceae), collected in Hainan island. One of them was shown to be a new diterpene of ent-kaurene type named anomaluone (I). Its structure was elucidated by spectral analyses and chem. transformation, and the stereochem. was determine by NOE technique. Another one is the known compound aurantiamide acetate.

Key words: CHEMICAL COMPOSITION, ACETIC ACID ESTER, AMIDES, INFRARED SPECTROPHOTOMETRY, INFRARED SPECTROPHOTOMETRY, MASS SPECTROGRAPHY, NUCLEAR MAGNETIC RESONANCE, DITERPENES, TETRACYCLIC DITERPENE, CHINESE DRUGS FOR ANTI-CANCINOMA (T.C.D.)

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