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化学学报
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化学学报 ›› 2002, Vol. 60 ›› Issue (4): 555-565.    下一篇

研究论文

含氟活泼亚甲基类化合物的研究

朱士正;王彦利;金桂芳   

  1. 中国科学院上海有机化学研究所.上海(200032)
  • 发布日期:2002-04-15

Study on the Fluorine-Containing Active Methylene Compounds

Zhu Shizheng;Wang Yanli;Jin Guifang   

  1. Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences.Shanghai(200032)
  • Published:2002-04-15

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被引次数

13 | 1

本研究工作包括下列三个方面的内容：（1）双-（全氟烷砜基）甲烷，双-（ 三氟双酰基）甲烷的合成及其反应。（2）2-氟烷基取代的醛和酮的合成和反应。 （3）氟烷基取代的1，3-二羰基化合物的化学转化及其在合成含氟杂环化合物中的 应用。

关键词: 甲烷 P, 砜, 醛, 酮, 氟, 杂环化合物, 羰基化合物

This review deals with recent progress in the study on the fluorine- containing active methylene compounds. It includes three parts: (1) Synthesis and reactions of bis(perfluoroalkanesulfonyl) methanes and bis(trifluoroacetyl) methane. (2) Preparation and reactions of 2- fluoroalkyl carbonyl compounds. (3) The chemical transformation of fluoroalkyl substituted 1,3-dicarbonyl compounds, and its application in the preparation of fluorine-containing heterocycles.

Key words: METHANE P, SULFONE, ALDEHYDES, KETONE P, FLUORINE, HETEROCYCLIC COMPOUNDS CARBONYL COMPOUNDS

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