化学学报 ›› 2002, Vol. 60 ›› Issue (6): 1125-1128. 上一篇    下一篇

研究论文

导电ZrO_2复合纳米材料的制备和表征

王利军;郭昌文;黄茜丹;赵伟;李全芝   

  1. 复旦大学化学系.上海(200433)
  • 发布日期:2002-06-15

Preparation and Characterization of Conductive ZrO_2 with Combined Nano-Structure

Wang LiJun;Guo Changwen;Huang Xidan;Zhao Wei;Li Quanzhi   

  1. Department of Chemistry, Fudan University.Shanghai(200433)
  • Published:2002-06-15

用溶胶-凝胶方法,结合后焙烧处理,得到系列ZrO_2纳米材料及其与碳膜组成 的复合材料,XRD,Raman,SEM及电电性能测试表明:复合ZrO_2纳米材料有较小的 粒径(6.85 nm),晶型为立方相,有较均匀的二次粒子分布,其中碳以碳膜形式 存在,复合材料有好的导电性能。将碳膜在823K氧化后,立方相转化为四方体相, 粒径增加,无导电性能。

关键词: 氧化锆, 复合材料, 纳米相材料, 溶胶-凝胶法, X射线衍射分析, 扫描电子显微镜, 导电性

Series of ZrO_2 nanomaterials and their combined materials with carbon membrane were obtained by Sol-Gel method followed by post- calcination. The test results of XRD, Raman and SEM show that the nanomaterials has as small size as 6.85 nm with cube phase, well- organized secondary distribution particles, and the combined materials exhibit good conductivity with carbon existing in membrane form. After carbon membrane was oxidated at 823 K, the cubic ZrO_2 was transformed into insulated tetragonal ZrO_2 with crystal size increasing.

Key words: ZIRCONIUM OXIDE, COMPOSITE MATERIALS, NANOPHASE MATERIALS, SOL-GEL PROCESS, XRD, SEM, ELECTRICAL CONDUCTIVITY

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