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化学学报
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化学学报 ›› 2007, Vol. 65 ›› Issue (12): 1149-1154. 上一篇    下一篇

研究论文

铂粒子修饰单壁碳纳米管/聚苯胺复合膜对甲醛的电催化氧化

王喆1, 朱赞赞1, 力虎林*,1,2   

  1. (1兰州大学化学化工学院 兰州 730000)
    (2南京航空航天大学材料科学与技术学院 南京 210016)
  • 投稿日期:2006-12-31 修回日期:2007-02-16 发布日期:2007-06-28
  • 通讯作者: 力虎林

Electrocatalytic Oxidation of Formaldehyde on SWNT/PANI Composite Film Modified by Platinum Particles

WANG Zhe1; ZHU Zan-Zan1; LI Hu-Lin*,1,2   

  1. (1 College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000)
    (2 College of Material Science and Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016)
  • Received:2006-12-31 Revised:2007-02-16 Published:2007-06-28
  • Contact: LI Hu-Lin

PDF

885

被引次数

56 | 10

在溶有单壁碳纳米管(SWNTs)的苯胺溶液中, 通过电化学共聚合法成功制备了单壁碳纳米管(SWNT)/聚苯胺(PANI)复合膜. 用电沉积法将铂沉积到SWNT/PANI复合膜上. 样品的成分和形貌分别用XRD和SEM表征. 四探针和电化学交流阻抗的研究表明被PANI包裹的SWNTs整齐地排列在复合膜中, 从而提高了复合膜的电导率, 促进了电荷转移. 循环伏安(CV)说明Pt修饰的SWNT/PANI复合膜对于甲醛氧化具有良好的电催化活性及稳定性. 研究结果表明SWNT/PANI复合膜是一种非常好的催化剂载体, 有着广泛的应用前景.

关键词: 单壁碳纳米管, 聚苯胺, 复合膜, 电催化甲醛, 电化学活性

Single-walled carbon nanotubes (SWNT)/polyaniline (PANI) composite films with good uniformity and dispersion were prepared by electrochemical copolymerization of aniline containing well- dissolved SWNTs. Pt was dispersed on the composite films by electrodeposition technique. The presence of SWNTs and platinum in the composite film was confirmed by XRD analysis and scanning electron microscopy (SEM). Four-point probe investigations and electrochemical impedance spectroscopys (EIS) revealed that the well arrangement of PANI coated SWNTs in these films enhanced electric conductivity and facilitated the charge-transfer of the composite films. Cyclic voltammograms (CV) and chronoamperogram showed that Pt-modified SWNT/PANI composite film performed higher electrocatalytic activity and better long-term stability than Pt-modified pure PANI film toward formaldehyde oxidation. The results imply that the SWNT/PANI composite film as a promising support material improves the electrocatalytic activity for formaldehyde oxidation greatly.

Key words: single-walled carbon nanotubes, polyaniline, composite film, formaldehyde electrooxidation, electrocatalytic activity