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化学学报
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化学学报 ›› 1994, Vol. 52 ›› Issue (5): 489-491. 上一篇    下一篇

研究论文

W离子注入Ni-Mo合金电极的析氢性能

张季爽;李青莲;吕瑶姣;言喜云   

  1. 湖南大学化学化工系.长沙(410082)
  • 发布日期:1994-05-15

Hydrogen evolution behavior of W-ion implanted Ni-Mo surface alloys electrodes

Zhang Jishuang;Li Qinglian;Lu Yaojiao;Yan Xiyun   

  1. Hunan Univ, Dept Chem & Chem Engn.Changsha(410082)
  • Published:1994-05-15

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703

被引次数

3

本文在镍基上电沉积Ni-Mo合金层,用W^+束注入,得到活性和稳定性极佳的新型析氢电极。

关键词: 析氢性能, 离子注入, 析氢电极, 电催化, 电子能谱

The electrodes containing Ni, W, Mo were obtained by implanten W into Ni-Mo surface alloys. The alloys was prepared by electrodepositing on Ni substrate. The hydrogen overvoltage decreasing comparing with mild steel is 235mV (48℃) in 0.5mol/dm^3 H~2SO~4 solution and 295mV (38℃) in 1mol/dm^3 NaOH solution. The cathodes showed stable potentials during water electrolysis by 300mA/cm^2 in acid medium more than 16 days. The strike-resistant stability of the cathodes was higher than others ones.

Key words: ION IMPLANTATION, ELECTRO-CATALYSIS, ELECTRON SPECTRUM

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