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化学学报
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化学学报 ›› 1999, Vol. 57 ›› Issue (9): 1038-1042. 上一篇    下一篇

研究论文

端羟基丁二烯-丙烯腈共低聚物控制组成的计算方法与合成

李志岩;杨震;张庆余   

  1. 吉林工学院.长春(130012);中国科学院长春应用化学研究所.长春(130022)
  • 发布日期:1999-09-15

Calculation formula and synthesis for controlling the composition of hydroxy-terminated butadiene acrylonitrile cooligomer

Li Zhiyan;Yang Zhen;Zhang Qingyu   

  1. Jilin College of Technology.Changchun(130012);Changchun Inst Appl Chem., CAS.Changchun(130022)
  • Published:1999-09-15

PDF

392

被引次数

4

针对二元共聚反应,在分批聚合中制备组成相同的共聚物,提出了为控制共聚物组成在反应过程中补加活性较大单体的计算方法。并根据这种方法合成了端羟基丁二烯-丙烯腈共低聚物。该方法也可用于其它二元共聚反应。

关键词: 计算方法, 共低聚物, 共聚物, 组成, 控制, 丁二烯, 丙烯腈

In preparing copolymer of the same composition by batch process in two-component copolymerization it is necessary to keep the monomer ratio constant by replenishing the fraction of the more reactive monomer. In this paper a calculation method for monomer feeding is derived, which is capable of controlling the composition of cooligomer during the course of reaction. Some cooligomers of acrylonitrile and butadiene with relatively the same compositions have been prepared using the replenishing method. The method would be useful for other two-component copolymerization process.

Key words: COMPUTATIONAL METHOD, COPOLYMERS, COMPOSITION, CONTROLS, BUTADIENE, ACRYLONITRILE

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