关键词: 水热反应, 分子筛, 催化活性, 硅, 钛, X射线衍射分析, 环己烯, 紫外分光光度法

Titanium-substituted mesoporous molecular sieve SB A-15 have been first successfully synthesized by a new direct approach under conventional hydrothermal conditions. The products obtained by reacting titanium butoxide with acetylacetone were used as the titanium precursor. By means of X-ray diffraction, nitrogen adsorption, UV-Vis diffuse reflectance, a successful isomorphous substitution of titanium in the silica framework of SBA-15 samples with Si/Ti = 50, 25, 20 has been proved, the substitution of Ti for Si does not change the highly ordered two-dimensional hexagonal mesostructure of SBA-15. Titanium is totally tetrahedral and highly dispersed. Higher titanium loading leads to the formation of titanium dioxide. Comparing with two- step preparation method, it shows that under the direct synthesis method, or one-step preparation method, titanium and silicon precursor hydrolyze harmoniously. Ti-SBA-15 demonstrates relatively high catalytic ability on the oxidation of cyclohexene. The differences of structure and catalytic ability between Ti-SBA-15 synthesized by one- step method and two-step method are explained

Key words: HYDRO-THERMAL REACTION, MOLECULAR SIEVE, CATALYST, SILICON, TITANIUM, XRD, CYCLOHEXENE, UV