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化学学报
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化学学报 ›› 2003, Vol. 61 ›› Issue (5): 765-773. 上一篇    下一篇

研究论文

新型以咔唑为主链的能量转移型发光聚合物

黄剑;牛于华;杨伟;侯琼;许怡赦;袁敏;曹镛   

  1. 华南理工大学高分子光电材料与器件研究所
  • 发布日期:2003-05-15

Novel Energy Transfer Carbazole-based Light-emitting Copolymers

Huang Jian;Niu Yuhua;Yang Wei;Hou Qiong;Xu Yishe;Yuan Min;Cao Yong   

  1. Institute of Polymer Optoelectronic Materials and Devices, South China University of Technology
  • Published:2003-05-15

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714

被引次数

51 | 7

用Suzuki偶合反应合成了一系列以咔唑为主链，与不同的芳香环和杂环化合物 共聚的新型电致发光无规共聚物．这些共聚物溶于普通的有机溶剂，发较强的荧光 ．咔唑链段为共聚物提供了很好的空穴传输和空穴注入性能．与咔唑共聚的窄能隙 单体，如蒽(ANT)、噻吩(Th)、2，1，3-苯并噻二唑(BTDZ)、2，1，3—苯并硒二唑 (BseDZ)和4，7—二噻吩—2，1，3—苯并噻二唑(DBT)在聚合物中含量小于50％时 成为陷阱中心．还观察到极为有效的分子内能量转移．由于共聚单体的能隙不同， 这些电致发光共聚物的发光范围可覆盖整个可见光谱区．研究结果表明，用咔唑作 为宽带主体，与少量低带隙单体共聚，有可能成为一种合成同时兼有优异空穴注入 特性，又能广泛调节发光颜色的新的发光聚合物体系．

关键词: 聚合物, 咔唑, 电致发光, 发光器件, 偶合反应, 能量传递

A series of novel electroluminescent polycarbazole-based main chain copolymers with varieties of aromatic rings and heterocycles as comonomer has been synthesized by Suzuki coupling reaction, The copolymers are soluble in common organic solvents and are highly fluorescent. Conjugated carbazole segment provides good hole-injection and hole-transport properties. Narrow band-gap heterocycles and aromatic rings, such as benzothiadiazole, benzoselenadi-azole, 4,7- dithien-2-yl-2,l,3-benzothiadiazole, thiophenes and anthracene in less than 50% of molar ratio in the copolymer were incorporated as a trapping center, The efficient energy transfer due to exciton trapping on the narrow band-gap sites was observed. The emission color can be tuned in entire visible region by carefully selecting the narrow band- gap comonomers. The use of conjugated polycarbazole as wide band-gap segment could provide a new way to combine good hole-injection properties along with color tuning ability.

Key words: POLYMER, CARBAZOLE, ELECTROLUMINESCENCE, LUMINESCENT DEVICES, COUPLING REACTION, ENERGY TRANSFER

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