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化学学报
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化学学报 ›› 2009, Vol. 67 ›› Issue (8): 863-868. 上一篇    下一篇

研究论文

钇(III)离子印迹聚合物的制备及性能研究

赖晓绮* 杨远奇 薛 珺

  

  1. (赣南师范学院化学与生命科学学院 赣州 341000)

  • 投稿日期:2008-07-22 修回日期:2008-12-05 发布日期:2009-04-28
  • 通讯作者: 赖晓绮

Preparation and Characteristics of the Yttrium(III)-ion Complex Molecularly Imprinted Polymer

Lai, Xiaoqi* Yang, Yuanqi Xue, Jun

  

  1. (College of Chemistry and Life Science, Gannan Normal University, Ganzhou 341000)

  • Received:2008-07-22 Revised:2008-12-05 Published:2009-04-28
  • Contact: LAI Xiao-Qi

PDF

1500

被引次数

31

以钇(III)离子作为模板, 以4-乙烯吡啶(4-VP)、乙酰丙酮(Hacac)和钇(III)形成的三元配合物为功能单体、乙二醇二甲基丙烯酸酯(EDMA)为交联剂, 采用本体聚合法合成了钇(III)离子配位分子印迹聚合物. 系统研究了印迹聚合物对钇(III)离子的吸附性和选择性. 结果表明, 印迹聚合物对钇(III)离子有很好的亲和性, 达到吸附平衡的时间为60 min, 最大吸附量为12.4 mg•g−1, 重复使用时性能稳定, 而且印迹聚合物对钇(III)离子具有较强的选择性识别能力.

关键词: 钇, 乙酰丙酮, 金属配合物, 印迹聚合物

A novel type of template molecularly imprinted polymer (MIP) was prepared by bulk polymerization using yttrium(III) ion as a template, yttrium(III)-4-vinylpyridine-acetylacetonate complex as a functional monomer and ethylene glycol dimethacrylate (EDMA) as a crosslinker. The selectivity and adsorption capacity for the Y(III) ions of Y(III)-MIP were systematically studied in this paper. The results obtained show that the sorption equilibrium was achieved in 60 min and the maximum sorption of yttrium(III) imprinted polymer was about 12.4 mg•g−1. When the Y(III)-MIP was repeatedly used, its adsorption capacity was kept. And the selectively adsorbed amount of Y(III) ion on Y(III)-MIP is higher than those of all other ions studied.

Key words: yttrium, acetylacetonate, metal complex, molecularly imprinted polymer