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化学学报
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化学学报 ›› 1989, Vol. 47 ›› Issue (1): 78-83. 上一篇    下一篇

研究论文

线性变位极谱法研究VII: CAEM过程配位吸附不可逆波理论

甘知行;陈莉莉;曹广营;张祖训   

  1. 南京大学化学系
  • 发布日期:1989-01-15

Investigation on polarography with linearly changing potential VII: On the theory for the adsorptive-complex irreversible waves with CAEM mechanism

GAN ZHIXING;CHEN LILI;CAO ANYING;ZHANG ZUXUN   

  • Published:1989-01-15

PDF

650

被引次数

46

金属配合物在电极上的吸附和反应机制与简单物质的吸附反应机制是不一样的, 因此其理论处理方法也不同. 本文推导了不可逆电极反应过程配位吸附波(CAEM过程)常规和导数谱方程式, 并以Cu^2^+-PAR-NaOH-丙三醇体系进行了验证, 理论与实验结果相符合.

关键词: 计算, 吸附, 铜络合物, 极谱分析, 金属络合物, 反应速度常数, 吡啶偶氮间苯二酚, 电化学反应, 线性变换, 甘油

Normal and derivative polarog. equations were derived for irreversible electrode reaction of adsorptive complexes. There was a good agreement between the experimental results and theor. calculation for Cu2+-PAR-NaOH-glycerin system.

Key words: CALCULATION, ADSORPTION, COPPER COMPLEX, POLAROGRAPHIC ANALYSIS, METAL COMPLEX, REACTION RATE CONSTANT, PYRIDINE AZO RESORCINOL, ELECTROCHEMICAL REACTION, LINEAR TRANSFORM, GLYCEROL

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