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化学学报
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化学学报 ›› 2005, Vol. 63 ›› Issue (16): 1541-1544. 上一篇    下一篇

研究简报

利用还原性多糖合成银纳米粒子

曹洁明*，郑明波，陆鹏，邓少高，陈勇平，文凡，郭静，张防，陶杰   

  1. (南京航空航天大学材料科学与技术学院 纳米材料研究所 南京 210016)
  • 投稿日期:2004-09-28 修回日期:2005-05-08 发布日期:2010-12-10
  • 通讯作者: 曹洁明

Synthesis of Silver Nanoparticles by Reductive Polysaccharides

CAO Jie-Ming*,ZHENG Ming-Bo,LU Peng,DENG Shao-Gao,CHEN Yong-Ping,WEN Fan,GUO Jing,ZHANG Fang,TAO Jie   

  1. (College of Materials Science and Technology, Nanomaterials Research Institute, Nanjing University of Aeronautics and Astronautics, Nanjing 210016)
  • Received:2004-09-28 Revised:2005-05-08 Published:2010-12-10
  • Contact: CAO Jie-Ming

PDF

2436

被引次数

22

利用还原性多糖为稳定剂、AgNO3为前驱物, 通过一条绿色途径合成银纳米粒子, 并探讨了纳米粒子的形成机理. 对多糖高浓度时制得的复合物在空气与氮气气氛下进行了热处理, 分别得到了银的大孔海绵体与银纳米粒子/碳的复合材料. 对产物进行了X射线衍射(XRD)、扫描电子显微镜(SEM)、透射电子显微镜(TEM)、紫外-可见分光光度(UV-vis)以及BET吸附表征.

关键词: 银纳米粒子, 多糖, 绿色化学, 银/碳复合材料

Silver nanoparticles have been prepared using reductive polysaccharides as protecting agents and silver nitrate as precursor via a facile green approach. The possible formation mechanism of silver nanoparticles was proposed. The composites synthesized at high concentration of polysaccharide were calcined in different atmosphere. Macroporous sponge of silver and silver nanoparticle/amorphous carbon composite have been obtained in air and nitrogen, respectively. The as-synthesized samples were characterized by XRD, SEM, TEM, UV-vis and BET adsorption methods.

Key words: silver nanoparticle, polysaccharide, green chemistry, silver/carbon composite