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化学学报
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化学学报 ›› 1987, Vol. 45 ›› Issue (6): 575-578. 上一篇    下一篇

研究论文

D2HEDTPA和D2EHPA萃取汞(II)的研究

宋魁元;宋玉林;李鸿图   

  1. 辽宁大学化学系
  • 发布日期:1987-06-15

The study of extraction of Hg(II) with di-2-ethylhexylphosphoric acid (D2EHPA) and di-2-ethylhexyldithiophosphoric acid (D2EHDTPA)

SONG KUIYUAN;SONG YULIN;LI HONGTU   

  • Published:1987-06-15

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关键词: 计算, 汞, 萃取剂, 量子化学, 光谱分析, 化学键, 数据, 成键, 磷酸二(乙基己基)酯, 磷酸二(乙基己基)酯

The extration of Hg2+ from HNO3 solution with (D2EHPA) and bis(2-ethylhexyl dithiophosphate (D2EHDTPA) was studied. The composition of extracted complex was determine by saturation and mol. ratio methods. The bonding of the extracted species is discussed on the basis of IR and NMR data. EHMO calcns. show that the extration capacities of the 2 extractants for Hg2+ are quite different.

Key words: CALCULATION, MERCURY, EXTRACTIVE AGENT, QUANTUM CHEMISTRY, SPECTROGRAPHIC ANALYSIS, CHEMICAL BONDS, DATA, BONDING, DI(ETHYLHEXYL) PHOSPHORIC ACID, DI(ETHYLHEXYL) PHOSPHORIC ACID

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