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化学学报
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化学学报 ›› 1987, Vol. 45 ›› Issue (1): 68-70. 上一篇    下一篇

研究论文

氧化碘苯间氨基苯甲酸锰(IV)四苯基卟啉配合物的合成

金日镇;高桂芬;金范龙   

  1. 中国科学院长春应用化学研究所
  • 发布日期:1987-01-15

Synthesis of iodosylbenzene, m-aminobenzoic acid tetraphenylprophinato manganese(IV)

JIN RIZHEN;GAO GUIFEN;JIN FANLONG   

  • Published:1987-01-15

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486

被引次数

2

高价锰卟啉配合物在温和条件下分解水,释放氧,是植物光体体II的可能模型化合物.我们选择间氨基苯甲酸作为轴向配体,在二氯甲烷中用氧化碘苯氧化H2NC6H4COOMn(III)TPP

关键词: 紫外分光光度法, 氨基酸, 卟吩 P, 红外分光光度法, 电子自旋共振谱法, 苯 P, 氯仿, 苯甲酸 P, 结构分析, 锰络合物

MnIV(m-O2CC6H4NH2)(TPP)(OIPh) (I, H2TPP = tetraphenylpropphyrin) was prepared by the oxidation of MnIII(m-O2CC6H4NH2)(TPP) in CH2Cl2 with iodosylbenzene. The visible absorption spectrum of I has an intense Soret band at 422 nm and a broad shoulder band at 522 nm. The IR spectrum has an intense absorption band at 580 cm-1 which is assigned to a Mn-O-O stretch and an absorption band at 1630 cm-1 which is assigned to the asym. stretching vibrations of carboxylate group. The ESR spectrum has a broad absorption band at g = 2.00 and an intense absorption band at ge^ = 3.26.

Key words: ULTRAVIOLET SPECTROPHOTOMETRY, AMINO ACID, PORPHINE P, INFRARED SPECTROPHOTOMETRY, ELECTRON SPIN RESONANCE SPECTROMETRY, BENZENE P, CHLOROFORM, BENZENECARBOXYLIC ACID P, STRUCTURAL ANALYSIS, MANGANESE COMPLEX

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