化学学报 ›› 2001, Vol. 59 ›› Issue (8): 1290-1293. 上一篇    下一篇

研究论文

直链醚-二甘肽型Schiff碱与稀土新配合物的合成、配 位作用与波谱

吴静;徐青;王奎武;姚克敏   

  1. 浙江大学化学系.杭州(310027)
  • 发布日期:2001-08-15

Synthesis, properties and magnetic resonance spectra of new rare earth complexes with noncylic polyther-glycylglycine schiff base

Wu Jing;Xu Qing;Wang Kuiwu;Yao Kemin   

  1. Zhejiang Univ, Dept Chem.Hangzhou(310027)
  • Published:2001-08-15

合成了稀土与四甘醇醛-二甘肽型Schiff碱(TAGLGL)形成的六种新配合物,在此配体中同时引入了C=N及HN—C=O基团。经元素分析、光谱等表征,确定该类多核配合物组成为:[Ln3(TAGLGL)(NO3)7]·4H2O(Ln=La,Nd,Sm,Gd,Yb,Y)。以液体1^HNMR谱、固体高分辨^13CNMR等方法,并结合Gd(Ⅲ)配合物的EPR波谱着重探讨了配位作用,配位数和晶体场强等。

关键词: 醚P, 四甘醇醛, 二肽, 甘氨酸, 多核络合物, 二甘肽, 席夫碱, 顺磁共振, 碳13核磁共振, 固体高分辨

Six novel rare earth complexes with noncyclic polyether- glycylglycine Schiff base (TAGLGL) have been synthesized with "step by step" method. They were confiremd by elemental analysis, IR, etc. and their formulas were established as [Ln3(TAGLGL)(NO3)7]·4H2O(Ln=La, Nd, Sm, Gd, Yb, Y). Owing to introducing a dipeptide bond with C=N and HN—C=O groups in the ligand, 1^H NMR and solid high resolution 13^C NMR with CPMAS and TOSS techniques and EPR spectra were used for elucidating the crystal field stregth, the symmetry in the obtained Gd(Ⅲ) complex andthe coordination of the donor atoms of the ligand with rare earth elements.

Key words: DIPEPTIDE, GLYCINE, POLYNUCLEAR COMPLEX, SCHIFF BASE, PARAMAGNETIC RESONANCE, CARBON-13 NMR SPECTROMETRY, RARE EARTH METAL COMPLEX, SPECTROMETRIC ANALYSIS

中图分类号: