化学学报 ›› 1988, Vol. 46 ›› Issue (8): 819-823. 上一篇    下一篇

研究论文

导电高分子薄膜修饰电极的研究I. 聚吡咯薄膜电极的电化学合成及行为

董绍俊;丁杰   

  1. 中国科学院长春应用化学研究所
  • 发布日期:1988-08-15

Studies on the modified electrode of conducting polymer film I. Polypyrrole film electrodes by electrochemical polymerization and their behaviours

DONG SHAOJUN;DING JIE   

  • Published:1988-08-15

利用在水溶液中的电化学聚合制备了聚吡咯烷、薄膜修饰电极. 讨论了对电化聚合的影响因素及薄膜修饰电极在不同电解质中的伏安特性, 从X-射线光电子能谱推测, 在吡咯的电化聚合过程中氧的参加引起在聚吡咯烷膜的结构中有羰基和羟基的生成.

关键词: 掺杂, 电解质, 聚合, X射线光电子谱法, 硝酸钾, 电化学反应, 杂环高聚物, 化学修饰电极, 电化学过程, 吡咯

Electroactive polypyrrole (I) film electrodes were prepared by electrochem. polymerisation in aqueous solns. The effects of monomer concentration, elec. potential, and potential scanning rate, no., and time on electropolymn. were studied, and voltammetric behavior of the electroactive film electrode in different electrolytes was discussed. The participation of O during electropolymn. of pyrrole in aqueous solution resulted in the formation of carbonyl and hydroxyl groups in the structure of I films was deduced form XPS measurement.

Key words: DOPE, ELECTROLYTE, POLYMERIZATION, X-RAY PHOTOELECTRON SPECTROMETRY, POTASSIUM NITRATE, ELECTROCHEMICAL REACTION, HETEROCYCLIC POLYMER, CHEMICAL MODIFIED ELECTRODE, ELECTROCHEMICAL PROCESS, PYRROLE

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