化学学报 ›› 2001, Vol. 59 ›› Issue (5): 751-754. 上一篇    下一篇

研究论文

双-(二烷硫基四硫富瓦烯二硫)金属配合物的合成及性质研究

杨更新;迟兴宝;王小刚;王建华   

  1. 西 北大学化学系
  • 发布日期:2001-05-15

Study on synthesis and properties of bis --(bisalkylthio--- tetrathiafulvalene ---dithiolate ) metal complex

Yang Gengxin;Chi Xingbao;Wang Xiaogang;Wang Jianhua   

  • Published:2001-05-15

合成了三种未见文献报道的双-(二烷硫基四硫富瓦烯二硫)金属配合物和三种新的四硫富瓦烯(TTF)桥联的双金属配合物,测定了它们的导电率,讨论了含Ni配合物的电导率优于含Cu,Hg配合物的原因。

关键词: 富瓦烯, 镍络合物, 铜络合物, 汞络合物, 电导率

Three new his -(bisalkylthio---tetrathiafulvalene ---dithiolate ) metal complex and three new bimetal complexes coordinated to TTF were synthesized. Their conductivity was determined. The reasons for the better conductivity of the Ni complexes than that of Cu and Hg were discussed.

Key words: FULVALENE (=BICYCLOPENTADIENYLI-DENE), NICKEL COMPLEX, COPPER COMPLEX, MERCURY COMPLEX, ELECTRICAL CONDUCTIVITY

中图分类号: