卤离子导向合成配位聚合物[Hg2X4(ppt)]n (X=I和Br; ppt=1-(4-吡啶基)-吡啶铵-4-硫醇盐)及不同的一维链状结构和三阶非线性光学响应

doi:10.6023/A13030272

化学学报 ›› 2013, Vol. 71 ›› Issue (06): 906-912.DOI: 10.6023/A13030272 上一篇下一篇

研究论文

卤离子导向合成配位聚合物[Hg₂X₄(ppt)]_n (X=I和Br; ppt=1-(4-吡啶基)-吡啶铵-4-硫醇盐)及不同的一维链状结构和三阶非线性光学响应

倪春燕^a,b, 陈阳^a, 李端秀^a, 任志刚^a, 李红喜^a, 孙真荣^c, 郎建平^a,b

a 苏州大学材料与化学化工学部苏州 215123;
b 中国科学院上海有机化学研究所金属有机化学国家重点实验室上海 200032;
c 华东师范大学物理系上海 200062

投稿日期:2013-03-14 发布日期:2013-05-02
通讯作者: 郎建平,jplang@suda.edu.cn; 陈阳, chemsunnychan@gmail.com; Tel.: 0512-65882865; Fax: 0512-65880089 E-mail:jplang@suda.edu.cn;chemsunnychan@gmail.com
基金资助:
项目受国家自然科学基金(No. 21171124)及上海有机化学研究所金属有机化学重点实验室开放基金(No. 201201006)资助.

Halide-Directed Synthesis of Coordination Polymers [Hg₂X₄(ppt)]_n (X=I and Br, ppt=1-(4-Pyridyl)-pyridinium-4-thiolate) with Different One-Dimensional Chain Structures and Third-Order Nonlinear Optical Properties

Ni Chunyan^a,b, Chen Yang^a, Li Duanxiu^a, Ren Zhigang^a, Li Hongxi^a, Sun Zhenrong^c, Lang Jianping^a,b

a College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123;
b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032;
c Department of Physics, East China Normal University, Shanghai 200062

Received:2013-03-14 Published:2013-05-02
Supported by:
Project supported by the National Natural Science Foundation of China (No. 21171124) and the State Key Laboratory of Organometallic Chemistry of Shanghai Institute of Organic Chemistry (No. 201201006).

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1. 卤离子导向合成配位聚合物[Hg₂X₄(ppt)]_n (X=I和Br; ppt=1-(4-吡啶基)-吡啶铵-4-硫醇盐)及不同的一维链状结构和三阶非线性光学响应.PDF(486KB)

摘要/Abstract

通过HgX₂ (X=I, Br)与4,4'-二吡啶基二硫化物(dpds)在乙腈中的溶剂热反应, 得到二个含1-(4-吡啶基)-吡啶铵-4-硫醇盐(ppt)的一维配位聚合物: [Hg₂I₄(ppt)]_n (1)和[Hg₂Br₄(ppt)]_n (2). 在化合物1和2结构中ppt配体是由dpds在溶剂热反应条件下通过dpds的S—S键和S—C键切断然后进行重排在原位形成的. 化合物1具有非中心对称的一维Z字型链状结构, 化合物2则具有中心对称的一维Z字型链状结构. 用飞秒简并四波混频法测定了1和2溶液的三阶非线性光学性质, 化合物1具有较强的非线性光学响应, 而化合物2却没有非线性光学响应, 这种性质的差异可能由于碘离子是较溴离子更好的电子授体, 化合物1有较小的HOMO-LUMO能级, 更易发生电子在体系间跃迁, 更有效使用三线激发态吸收.

关键词: 卤离子导向, 配位聚合物, 溶解热合成, 结构, 非线性光学

Solvothermal reactions of HgX₂ (X=I, Br) with 4,4'-dipyridyl disulfide (dpds) in acetonitrile gave rise to two one-dimensional polymers [Hg₂X₄(ppt)]_n [ppt=1-(4-pyridyl)-pyridinium-4-thiolate; X=I (1), Br (2)]. In the structures of 1 and 2, the ppt ligand was in situ generated from the Hg(II)-engaged cleavage of both S—S and S—C bonds of dpds and the subsequent rearrangement reactions under solvothermal conditions. Although compounds 1 and 2 have similar chemical formula, 1 crystallizes in the orthorhombic space group Ima2 and holds a 1D non-centrosymmetric zigzag chain while 2 crystallizes in the orthorhombic space group Pnma and has a 1D centrosymmetric zigzag chain. Such a difference in structural symmetry between 1 and 2 may be due to the fact that the radius of iodide is larger than that of bromide. The third-order nonlinear optical (NLO) behaviours of 1 and 2 in DMF were investigated by using femtosecond degenerate four-wave mixing technique. Compound 1 exhibited relatively strong NLO responses while compound 2 showed nothing. Such a remarkable difference in the NLO property may be due to the fact that iodide is a better electron donor than bromide, which allows more efficient spin-orbital coupling, and facilitates intersystem crossing and more efficient usage of triplet excited state absorption.

Key words: halide-directed, coordination polymer, solvothermal synthesis, structure, nonlinear optical properties

引用此文

倪春燕, 陈阳, 李端秀, 任志刚, 李红喜, 孙真荣, 郎建平. 卤离子导向合成配位聚合物[Hg₂X₄(ppt)]_n (X=I和Br; ppt=1-(4-吡啶基)-吡啶铵-4-硫醇盐)及不同的一维链状结构和三阶非线性光学响应[J]. 化学学报, 2013, 71(06): 906-912.

Ni Chunyan, Chen Yang, Li Duanxiu, Ren Zhigang, Li Hongxi, Sun Zhenrong, Lang Jianping. Halide-Directed Synthesis of Coordination Polymers [Hg₂X₄(ppt)]_n (X=I and Br, ppt=1-(4-Pyridyl)-pyridinium-4-thiolate) with Different One-Dimensional Chain Structures and Third-Order Nonlinear Optical Properties[J]. Acta Chimica Sinica, 2013, 71(06): 906-912.

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参考文献

[1] (a) Chen, X. M.; Tong, M. L. Acc. Chem. Res. 2007, 40, 162;

(b) Zhang, J. P.; Zhang, Y. B.; Lin, J. B.; Chen, X. M. Chem. Rev. 2012, 112, 1001;

(c) Wang, C.; Zhang, T.; Lin, W. B. Chem. Rev. 2012, 112, 1084;

(d) Cohen, S. M. Chem. Rev. 2012, 112, 970.

[2] (a) Zhao, H.; Qu, Z. R.; Ye, H. Y.; Xiong, R. G. Chem. Soc. Rev. 2008, 37, 84;

(b) Goto, Y.; Sato, H.; Shinkai, S.; Sada, K. J. Am. Chem. Soc. 2008, 130, 14354;

(c) Zhang, X. M. Coord. Chem. Rev. 2005, 249, 1201;

(d) Wang, X. Y.; Wang, Z. M.; Gao, S. Chem. Commun. 2007, 1127.

[3] (a) Papaefstathiou, G. S.; Zhong, Z. M.; Geng, L.; MacGillivray, L. R. J. Am. Chem. Soc. 2004, 126, 9158;

(b) Chu, Q. L.; Swenson, D. C.; MacGillivray, L. R. Angew. Chem., Int. Ed. 2005, 44, 3569;

(c) Han, Y. F.; Lin, Y. J.; Jia, W. G.; Wang, G. L.; Jin, G. X. Chem. Commun. 2008, 1807;

(d) Georgiev, I. G.; MacGillivray, L. R. Chem. Soc. Rev. 2007, 36, 1239;

(e) Vittal, J. J. Coord. Chem. Rev. 2007, 251, 1781;

(f) Mir, M. H.; Koh, L. L.; Tan, G. K.; Vittal, J. J. Angew. Chem., Int. Ed. 2010, 49, 390;

(g) Liu, D.; Ren, Z. G.; Li, H. X.; Lang, J. P.; Li, N. Y.; Abrahams, B. F. Angew. Chem., Int. Ed. 2010, 49, 4767;

(h) Liu, D.; Lang, J. P.; Abrahams, B. F. Chem. Commun. 2013, 49, 2682.

[4] (a) Zhu, H. B.; Gou, S. H. Coord. Chem. Rev. 2011, 255, 318;

(b) Horikoshi, R.; Mochida, T. Coord. Chem. Rev. 2006, 250, 2595;

(c) Zhu, Q.; Sheng, T.; Tan, C.; Hu, S.; Fu, R.; Wu, X. Inorg. Chem. 2011, 50, 7618;

(d) Carballo, R.; Covelo, B.; Fernández-Hermida, N.; Lago, A. B.; Vázquez-López, E. M. CrystEngComm 2009, 11, 817;

(e) Houng, S. Y.; Jung, H. Y.; Jae, I. K.; Eui, K. K.; Chang, S. H. Eur. J. Inorg. Chem. 2008, 3123;

(f) Li, H. X.; Wu, H. Z.; Zhang, W. H.; Ren, Z. G.; Zhang, Y.; Lang, J. P. Chem. Commun. 2007, 5052.

[5] (a) Han, L.; Bu, X.; Zhang, Q.; Feng, P. Inorg. Chem. 2006, 45, 5736;

(b) Wang, J.; Zhang, Y. H.; Li, H. X.; Lin, Z. J.; Tong, M. L. Cryst. Growth Des. 2007, 7, 2352;

(c) Wang, J.; Zheng, S. L.; Hu, S.; Zhang, Y. H.; Tong, M. L. Inorg. Chem. 2007, 46, 795;

(d) Ma, L. F.; Wang, Y. Y.; Wang, L. Y.; Lu, D. H.; Batten, S. R.; Wang, J. G. Cryst. Growth Des. 2009, 9, 2036;

(e) Ma, L. F.; Wang, L. Y.; Du, M. CrystEngComm 2009, 11, 2593.

[6] Chen, Y.; Wang, Z. O.; Ren, Z. G.; Li, H. X.; Li, D. X.; Liu, D.; Zhang, Y.; Lang, J. P. Cryst. Growth Des. 2009, 9, 4963.

[7] (a) Lang, J. P.; Xu, Q. F.; Zhang, W. H.; Li, H. X.; Ren, Z. G.; Chen, J. X.; Zhang, Y. Inorg. Chem. 2006, 45, 10487;

(b) Tang, X. Y.; Li, H. X.; Chen, J. X.; Ren, Z. G.; Lang, J. P. Coord. Chem. Rev. 2008, 252, 2026.

[8] Nakamoto, K. In Infrared and Raman Spectra of Inorganic and Coordination Compounds, 4th ed., Wiley, New York, 1986.

[9] Chen, J. X.; Zhang, W. H.; Tang, X. Y.; Ren, Z. G.; Zhang, Y.; Lang, J. P. Inorg. Chem. 2006, 45, 2568.

[10] Lü, X. Q.; Pan, M.; He, J. R.; Cai, Y. P.; Kang, B. S.; Su, C. Y. CrystEngComm 2006, 8, 827.

[11] Svensson, P. H.; Kloo, L. Inorg. Chem. 1999, 38, 3390.

[12] Dean, P. A. W.; Vittal, J. J.; Wu, Y. Inorg. Chem. 1994, 33, 2180.

[13] Wang, X. F.; Lv, Y.; Okamura, T. A.; Kawaguchi, H.; Wu, G.; Sun, W. Y.; Ueyama, N. Cryst. Growth Des. 2007, 7, 1125.

[14] Mbogo, S. A.; Lobana, T. S.; McWhinnie, W. R.; Greaves, M. R.; Hamor, T. A. J. Organomet. Chem. 1990, 395, 167.

[15] (a) Yang, Y.; Samoc, M.; Prasad, P. N. J. Chem. Phys. 1991, 94, 5282;

(b) Orezyk, M. E.; Samoc, M.; Swiatkiewicz, J.; Prasad, P. N. J. Chem. Phys. 1993, 98, 2524;

(c) Jenekhe, S. A.; Lo, S. K.; Flom, S. R. Appl. Phys. Lett. 1989, 54, 2524;

(d) Mandal, B. K.; Bihari, B.; Sinha, A. K.; Kamath, M.; Chen, L. Appl. Phys. Lett. 1995, 66, 932.

[16] (a) Swiatkiewicz, J.; Prasad, P. N.; Reinhardt, B. A. Opt. Commun. 1998, 157, 135;

(b) Kim, O. K.; Lee, K. S.; Woo, H. Y.; Kim, K. S.; He, G. S.; Swiatkiewicz, J.; Prasad, P. N. Chem. Mater. 2000, 12, 284.

[17] (a) Lü, X.; Chen, X.; Ren. Z. G.; Lang, J. P.; Liu, D.; Sun, Z. R. Dalton Trans. 2011, 40, 7983;

(b) Ren, Z. G.; Sun, S.; Dai, M.; Wang, H. F.; Lü, C. N.; Lang, J. P.; Sun, Z. R. Dalton Trans. 2011, 40, 8391;

(c) Zhang, W. H.; Chen, J. X.; Li, H. X.; Wu, B.; Tang, X. Y.; Ren, Z. G.; Zhang, Y.; Lang, J. P.; Sun, Z. R. J. Organomet. Chem. 2005, 690, 394.

[18] Zhai, T.; Lawson, C. M.; Gale, D. C.; Gray, G. M. Opt. Mater. 1995, 4, 455.

[19] (a) Shi, S.; Lin, Z.; Mo, Y.; Xin, X. Q. J. Phys. Chem. 1996, 100, 10696;

(b) Shi, S.; Ji, W.; Tang, S. H.; Lang, J. P.; Xin, X. Q. J. Am. Chem. Soc. 1994, 116, 3615;

(c) Zhang, C.; Song, Y. L.; Wang, X. Coord. Chem. Rev. 2007, 251, 1111;

(d) Shi, S. In Optoelectronic Properties of Inorganic Compounds, Eds.: Roundhill, D. M.; Fackler, J. P. Jr., Plenum Press, New York, 1998, pp. 55～105;

(e) Zhang, Q. F.; Xiong, Y. N.; Lai, T. S.; Ji, W.; Xin, X. Q. J. Phys. Chem. B 2000, 104, 3446.

[20] Sheldrick, G. M. Acta Cryst. 2008, A64, 112.

卤离子导向合成配位聚合物[Hg₂X₄(ppt)]_n (X=I和Br; ppt=1-(4-吡啶基)-吡啶铵-4-硫醇盐)及不同的一维链状结构和三阶非线性光学响应

Halide-Directed Synthesis of Coordination Polymers [Hg₂X₄(ppt)]_n (X=I and Br, ppt=1-(4-Pyridyl)-pyridinium-4-thiolate) with Different One-Dimensional Chain Structures and Third-Order Nonlinear Optical Properties

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